Standard Enthalpies and Heat Capacities of Solution of Urea and Tetramethylurea in Water
Тип публикации: Journal Article
Дата публикации: 2010-04-13
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wos Q2
БС2
SJR: 0.449
CiteScore: 4
Impact factor: 2.1
ISSN: 00219568, 15205134
General Chemistry
General Chemical Engineering
Краткое описание
This paper presents the results of accurate measurements of the enthalpies of solution of a typical hydrophilic solute, urea, and its hydrophobic derivative, tetramethylurea, in water in the temperature range of (278.15 to 338.15) K. The standard enthalpies and heat capacities of solution are computed and compared with available literature values. Our results do indicate that the standard heat capacity of the solution of urea is very small, but it changes its sign at about the temperature minimum of the water heat capacity at constant pressure, while the heat capacity of tetramethylurea solution in water is large, positive, and independent of the temperature.
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Kustov A. V., Smirnova N. L. Standard Enthalpies and Heat Capacities of Solution of Urea and Tetramethylurea in Water // Journal of Chemical & Engineering Data. 2010. Vol. 55. No. 9. pp. 3055-3058.
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Kustov A. V., Smirnova N. L. Standard Enthalpies and Heat Capacities of Solution of Urea and Tetramethylurea in Water // Journal of Chemical & Engineering Data. 2010. Vol. 55. No. 9. pp. 3055-3058.
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TY - JOUR
DO - 10.1021/je9010689
UR - https://doi.org/10.1021/je9010689
TI - Standard Enthalpies and Heat Capacities of Solution of Urea and Tetramethylurea in Water
T2 - Journal of Chemical & Engineering Data
AU - Kustov, Andrey V
AU - Smirnova, Nataliya L
PY - 2010
DA - 2010/04/13
PB - American Chemical Society (ACS)
SP - 3055-3058
IS - 9
VL - 55
SN - 0021-9568
SN - 1520-5134
ER -
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@article{2010_Kustov,
author = {Andrey V Kustov and Nataliya L Smirnova},
title = {Standard Enthalpies and Heat Capacities of Solution of Urea and Tetramethylurea in Water},
journal = {Journal of Chemical & Engineering Data},
year = {2010},
volume = {55},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/je9010689},
number = {9},
pages = {3055--3058},
doi = {10.1021/je9010689}
}
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MLA
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Kustov, Andrey V., and Nataliya L Smirnova. “Standard Enthalpies and Heat Capacities of Solution of Urea and Tetramethylurea in Water.” Journal of Chemical & Engineering Data, vol. 55, no. 9, Apr. 2010, pp. 3055-3058. https://doi.org/10.1021/je9010689.