Measurement of Activity Coefficients at Infinite Dilution Using Gas−Liquid Chromatography. 10. Results for Various Solutes with the Stationary Phases Dimethyl Sulfoxide, Propylene Carbonate, and N-Ethylformamide
Publication type: Journal Article
Publication date: 1999-11-01
scimago Q2
wos Q2
SJR: 0.449
CiteScore: 4.0
Impact factor: 2.1
ISSN: 00219568, 15205134
General Chemistry
General Chemical Engineering
Abstract
Using gas−liquid chromatography (GLC), activity coefficients at infinite dilution have been measured for 37 solutes (alkanes, alkenes, cyclic hydrocarbons, aromatic hydrocarbons, alcohols, ketones, ethers, aldehydes, esters, and halocarbons) in the solvents dimethyl sulfoxide, propylene carbonate, and N-ethylformamide. The measurements were carried out in the temperature range between 303.15 and 333.15 K. The obtained γ∞ values are compared with published data, and the observed temperature dependence of the limiting activity coefficients is confirmed using excess enthalpy data. Furthermore, the selectivities and capacities of the investigated solvents for the separation of aliphatics from aromatics are compared.
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Topphoff M., Gruber D., Gmehling J. Measurement of Activity Coefficients at Infinite Dilution Using Gas−Liquid Chromatography. 10. Results for Various Solutes with the Stationary Phases Dimethyl Sulfoxide, Propylene Carbonate, and N-Ethylformamide // Journal of Chemical & Engineering Data. 1999. Vol. 44. No. 6. pp. 1355-1359.
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Topphoff M., Gruber D., Gmehling J. Measurement of Activity Coefficients at Infinite Dilution Using Gas−Liquid Chromatography. 10. Results for Various Solutes with the Stationary Phases Dimethyl Sulfoxide, Propylene Carbonate, and N-Ethylformamide // Journal of Chemical & Engineering Data. 1999. Vol. 44. No. 6. pp. 1355-1359.
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RIS
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TY - JOUR
DO - 10.1021/je990145p
UR - https://doi.org/10.1021/je990145p
TI - Measurement of Activity Coefficients at Infinite Dilution Using Gas−Liquid Chromatography. 10. Results for Various Solutes with the Stationary Phases Dimethyl Sulfoxide, Propylene Carbonate, and N-Ethylformamide
T2 - Journal of Chemical & Engineering Data
AU - Topphoff, Magnus
AU - Gruber, Detlef
AU - Gmehling, Jürgen
PY - 1999
DA - 1999/11/01
PB - American Chemical Society (ACS)
SP - 1355-1359
IS - 6
VL - 44
SN - 0021-9568
SN - 1520-5134
ER -
Cite this
BibTex (up to 50 authors)
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@article{1999_Topphoff,
author = {Magnus Topphoff and Detlef Gruber and Jürgen Gmehling},
title = {Measurement of Activity Coefficients at Infinite Dilution Using Gas−Liquid Chromatography. 10. Results for Various Solutes with the Stationary Phases Dimethyl Sulfoxide, Propylene Carbonate, and N-Ethylformamide},
journal = {Journal of Chemical & Engineering Data},
year = {1999},
volume = {44},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/je990145p},
number = {6},
pages = {1355--1359},
doi = {10.1021/je990145p}
}
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MLA
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Topphoff, Magnus, et al. “Measurement of Activity Coefficients at Infinite Dilution Using Gas−Liquid Chromatography. 10. Results for Various Solutes with the Stationary Phases Dimethyl Sulfoxide, Propylene Carbonate, and N-Ethylformamide.” Journal of Chemical & Engineering Data, vol. 44, no. 6, Nov. 1999, pp. 1355-1359. https://doi.org/10.1021/je990145p.