Thermolysis of 4-Methyl-4-(1-propenyl)malonyl Peroxide: Mechanistic Limits to Chemiluminescence Efficiency.
Тип публикации: Journal Article
Дата публикации: 1985-10-01
scimago Q2
wos Q1
БС1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
Organic Chemistry
Краткое описание
Abstract : The preparation and thermal chemistry of 4-methyl-4-(1-propenyl)malonyl peroxide (3) is described. Thermolysis in acetonitrile at 84 C gives 2,4-dimethylbut-2-ene-4-olide in 45% yield and oligomeric ester derived from an intermediate alpha-lactone in 55% yield. The reaction of 3 can be catalyzed by aromatic hydrocarbons such as perylene. Under these conditions weak chemiluminescence results. The mechanism for light generation is identified as chemically initiated electron-exchange luminescence (CIEEL). Application of the CIEEL mechanism to 3 reveals an important limitation to light generation by this path. Originator-supplied keywords include: Chemiluminescence, Malonyl peroxide, Electron transfer.
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Porter J. E., Schuster G. B. Thermolysis of 4-Methyl-4-(1-propenyl)malonyl Peroxide: Mechanistic Limits to Chemiluminescence Efficiency. // Journal of Organic Chemistry. 1985. Vol. 50. No. 21. pp. 4068-4071.
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Porter J. E., Schuster G. B. Thermolysis of 4-Methyl-4-(1-propenyl)malonyl Peroxide: Mechanistic Limits to Chemiluminescence Efficiency. // Journal of Organic Chemistry. 1985. Vol. 50. No. 21. pp. 4068-4071.
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TY - JOUR
DO - 10.1021/jo00221a021
UR - https://doi.org/10.1021/jo00221a021
TI - Thermolysis of 4-Methyl-4-(1-propenyl)malonyl Peroxide: Mechanistic Limits to Chemiluminescence Efficiency.
T2 - Journal of Organic Chemistry
AU - Porter, Judith E
AU - Schuster, Gary B.
PY - 1985
DA - 1985/10/01
PB - American Chemical Society (ACS)
SP - 4068-4071
IS - 21
VL - 50
SN - 0022-3263
SN - 1520-6904
ER -
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@article{1985_Porter,
author = {Judith E Porter and Gary B. Schuster},
title = {Thermolysis of 4-Methyl-4-(1-propenyl)malonyl Peroxide: Mechanistic Limits to Chemiluminescence Efficiency.},
journal = {Journal of Organic Chemistry},
year = {1985},
volume = {50},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/jo00221a021},
number = {21},
pages = {4068--4071},
doi = {10.1021/jo00221a021}
}
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Porter, Judith E., and Gary B. Schuster. “Thermolysis of 4-Methyl-4-(1-propenyl)malonyl Peroxide: Mechanistic Limits to Chemiluminescence Efficiency..” Journal of Organic Chemistry, vol. 50, no. 21, Oct. 1985, pp. 4068-4071. https://doi.org/10.1021/jo00221a021.