American Chemical Society (ACS)
Journal of Organic Chemistry
,  том 68 ,  издание 8 ,  страницы 3139-3144

Reaction of Some Strong N-Bases with Chloropentafluorobenzene in the Presence of Water Molecules

Тип публикации: Journal Article
Дата публикации: 2003-03-19
American Chemical Society (ACS)
scimago Q2
wos Q1
БС1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
Organic Chemistry
Краткое описание
Products of reactions between chloropentafluorobenzene and strong N-bases (DBN, DBU, TBD, and MTBD) in polar aprotic solvents and in the presence of water were isolated and identified by analytical and spectroscopic methods. The products of these dehydrohalogenation reactions are apropriate lactams, and if the TBD N-base is used, a condensation occurs with formation of benzimidazole derivative. All the products are not formed directly in the nucleophilic substitution by N-bases but after the hydrolyses of the N-bases with formation of amines known as hard nucleophiles.
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Gierczyk B., SCHROEDER G., Brzezinski B. Reaction of Some Strong N-Bases with Chloropentafluorobenzene in the Presence of Water Molecules // Journal of Organic Chemistry. 2003. Vol. 68. No. 8. pp. 3139-3144.
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Gierczyk B., SCHROEDER G., Brzezinski B. Reaction of Some Strong N-Bases with Chloropentafluorobenzene in the Presence of Water Molecules // Journal of Organic Chemistry. 2003. Vol. 68. No. 8. pp. 3139-3144.
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TY - JOUR
DO - 10.1021/jo026899f
UR - https://doi.org/10.1021/jo026899f
TI - Reaction of Some Strong N-Bases with Chloropentafluorobenzene in the Presence of Water Molecules
T2 - Journal of Organic Chemistry
AU - Gierczyk, Błażej
AU - SCHROEDER, G.
AU - Brzezinski, Bogumił
PY - 2003
DA - 2003/03/19
PB - American Chemical Society (ACS)
SP - 3139-3144
IS - 8
VL - 68
PMID - 12688784
SN - 0022-3263
SN - 1520-6904
ER -
BibTex |
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@article{2003_Gierczyk,
author = {Błażej Gierczyk and G. SCHROEDER and Bogumił Brzezinski},
title = {Reaction of Some Strong N-Bases with Chloropentafluorobenzene in the Presence of Water Molecules},
journal = {Journal of Organic Chemistry},
year = {2003},
volume = {68},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/jo026899f},
number = {8},
pages = {3139--3144},
doi = {10.1021/jo026899f}
}
MLA
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Gierczyk, Błażej, et al. “Reaction of Some Strong N-Bases with Chloropentafluorobenzene in the Presence of Water Molecules.” Journal of Organic Chemistry, vol. 68, no. 8, Mar. 2003, pp. 3139-3144. https://doi.org/10.1021/jo026899f.