Pentafluorophenyl Transfer: A New Group-Transfer Reaction in Organoborate Salts
Publication type: Journal Article
Publication date: 2005-11-17
scimago Q2
wos Q1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
16355982
Organic Chemistry
Abstract
[reaction: see text] Irradiation of isoquinolinium hydroxytris(pentafluorophenyl)borate, 1, and phenanthridium hydroxytris(pentafluorophenyl)borate, 2, in either CH2Cl2 or CH3CN resulted in C6F5 transfer to the isoquinolinium and phenanthridium cations, generating 2-methyl-1-(2,3,4,5,6-pentafluorophenyl)-1,2-dihydroisoquinoline, 3, and 2-methyl-1-(2,3,4,5,6-pentafluorophenyl)-1,2-dihydrophenanthridine, 4, respectively. In addition, photogeneration of H2O x B(C6F5)3 resulted from 1. Photogeneration of C6F5-C6F4H from HO-B(C6F5)3(-) and of C6H5-C6F4H from C6H5-B(C6F5)3(-) was discovered.
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28
Total citations:
28
Citations from 2025:
1
(3.57%)
The most citing journal
Citations in journal:
3
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MLA
Cite this
GOST
Copy
Hewavitharanage P., Danilov E., NECKERS D. C. Pentafluorophenyl Transfer: A New Group-Transfer Reaction in Organoborate Salts // Journal of Organic Chemistry. 2005. Vol. 70. No. 26. pp. 10653-10659.
GOST all authors (up to 50)
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Hewavitharanage P., Danilov E., NECKERS D. C. Pentafluorophenyl Transfer: A New Group-Transfer Reaction in Organoborate Salts // Journal of Organic Chemistry. 2005. Vol. 70. No. 26. pp. 10653-10659.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/jo050695s
UR - https://doi.org/10.1021/jo050695s
TI - Pentafluorophenyl Transfer: A New Group-Transfer Reaction in Organoborate Salts
T2 - Journal of Organic Chemistry
AU - Hewavitharanage, Priyadarshine
AU - Danilov, Evgeny
AU - NECKERS, DOUGLAS C.
PY - 2005
DA - 2005/11/17
PB - American Chemical Society (ACS)
SP - 10653-10659
IS - 26
VL - 70
PMID - 16355982
SN - 0022-3263
SN - 1520-6904
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2005_Hewavitharanage,
author = {Priyadarshine Hewavitharanage and Evgeny Danilov and DOUGLAS C. NECKERS},
title = {Pentafluorophenyl Transfer: A New Group-Transfer Reaction in Organoborate Salts},
journal = {Journal of Organic Chemistry},
year = {2005},
volume = {70},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/jo050695s},
number = {26},
pages = {10653--10659},
doi = {10.1021/jo050695s}
}
Cite this
MLA
Copy
Hewavitharanage, Priyadarshine, et al. “Pentafluorophenyl Transfer: A New Group-Transfer Reaction in Organoborate Salts.” Journal of Organic Chemistry, vol. 70, no. 26, Nov. 2005, pp. 10653-10659. https://doi.org/10.1021/jo050695s.