Practical synthesis of chiral vinylphosphine oxides by direct nucleophilic substitution. Stereodivergent synthesis of aminophosphine ligands.
Тип публикации: Journal Article
Дата публикации: 2006-02-22
scimago Q2
wos Q1
БС1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
16526799
Organic Chemistry
Краткое описание
[reaction: see text] A practical synthesis of optically pure alkylphenylvinylphosphine oxides is described, utilizing a nucleophilic displacement at phosphorus to install the vinyl moiety. The products were used to prepare classes of P-stereogenic aminophosphine (PN) and aminohydroxyphosphine (PNO) ligands. Stereocontrol can be exerted at various stages of the synthesis, to provide specific combinations of chirality in the final product. The effect of the stereogenic phosphorus and match-mismatch of chiralities of PNO ligands were examined in the asymmetric ruthenium-catalyzed hydrogen transfer reduction of three aryl ketones.
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ГОСТ
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Oliana M. et al. Practical synthesis of chiral vinylphosphine oxides by direct nucleophilic substitution. Stereodivergent synthesis of aminophosphine ligands. // Journal of Organic Chemistry. 2006. Vol. 71. No. 6. pp. 2472-2479.
ГОСТ со всеми авторами (до 50)
Скопировать
Oliana M., King F., Horton P. J., Hursthouse M. B., Hii K. K. Practical synthesis of chiral vinylphosphine oxides by direct nucleophilic substitution. Stereodivergent synthesis of aminophosphine ligands. // Journal of Organic Chemistry. 2006. Vol. 71. No. 6. pp. 2472-2479.
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RIS
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TY - JOUR
DO - 10.1021/jo052575q
UR - https://doi.org/10.1021/jo052575q
TI - Practical synthesis of chiral vinylphosphine oxides by direct nucleophilic substitution. Stereodivergent synthesis of aminophosphine ligands.
T2 - Journal of Organic Chemistry
AU - Oliana, Marco
AU - King, Frank
AU - Horton, Peter John
AU - Hursthouse, M. B.
AU - Hii, King K.
PY - 2006
DA - 2006/02/22
PB - American Chemical Society (ACS)
SP - 2472-2479
IS - 6
VL - 71
PMID - 16526799
SN - 0022-3263
SN - 1520-6904
ER -
Цитировать
BibTex (до 50 авторов)
Скопировать
@article{2006_Oliana,
author = {Marco Oliana and Frank King and Peter John Horton and M. B. Hursthouse and King K. Hii},
title = {Practical synthesis of chiral vinylphosphine oxides by direct nucleophilic substitution. Stereodivergent synthesis of aminophosphine ligands.},
journal = {Journal of Organic Chemistry},
year = {2006},
volume = {71},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/jo052575q},
number = {6},
pages = {2472--2479},
doi = {10.1021/jo052575q}
}
Цитировать
MLA
Скопировать
Oliana, Marco, et al. “Practical synthesis of chiral vinylphosphine oxides by direct nucleophilic substitution. Stereodivergent synthesis of aminophosphine ligands..” Journal of Organic Chemistry, vol. 71, no. 6, Feb. 2006, pp. 2472-2479. https://doi.org/10.1021/jo052575q.