Fragmentation of Trifluoromethylated Alkenes and Acetylenes by N,N-Binucleophiles. Synthesis of Imidazolines or Imidazolidines (Oxazolidines) Controlled by Substituent
Aleksey V Shastin
2
,
Elizabeth S. Balenkova
1
,
Evgeniy V Kondrashov
3
,
Igor Ushakov
3
,
Alexander Yu. Rulev
3
Publication type: Journal Article
Publication date: 2010-07-29
scimago Q2
wos Q1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
20669939
Organic Chemistry
Abstract
The reaction of beta-halogeno-beta-polyfluoromethylstyrenes with N,N- or N,O-binucleophiles leads to unexpected fragmentation products (imidazolines) or to heterocyclization giving CF(3)-substituted imidazolidines (N,N-) and oxazolidines (N,O-) depending on aryl substituent. The scope and the reaction mechanism are discussed.
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Total citations:
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Citations from 2024:
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Cite this
GOST
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Nenajdenko V. G. et al. Fragmentation of Trifluoromethylated Alkenes and Acetylenes by N,N-Binucleophiles. Synthesis of Imidazolines or Imidazolidines (Oxazolidines) Controlled by Substituent // Journal of Organic Chemistry. 2010. Vol. 75. No. 16. pp. 5679-5688.
GOST all authors (up to 50)
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Nenajdenko V. G., Muzalevskiy V. M., Shastin A. V., Balenkova E. S., Kondrashov E. V., Ushakov I., Rulev A. Y. Fragmentation of Trifluoromethylated Alkenes and Acetylenes by N,N-Binucleophiles. Synthesis of Imidazolines or Imidazolidines (Oxazolidines) Controlled by Substituent // Journal of Organic Chemistry. 2010. Vol. 75. No. 16. pp. 5679-5688.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/jo101107t
UR - https://doi.org/10.1021/jo101107t
TI - Fragmentation of Trifluoromethylated Alkenes and Acetylenes by N,N-Binucleophiles. Synthesis of Imidazolines or Imidazolidines (Oxazolidines) Controlled by Substituent
T2 - Journal of Organic Chemistry
AU - Nenajdenko, Valentine G.
AU - Muzalevskiy, Vasily M.
AU - Shastin, Aleksey V
AU - Balenkova, Elizabeth S.
AU - Kondrashov, Evgeniy V
AU - Ushakov, Igor
AU - Rulev, Alexander Yu.
PY - 2010
DA - 2010/07/29
PB - American Chemical Society (ACS)
SP - 5679-5688
IS - 16
VL - 75
PMID - 20669939
SN - 0022-3263
SN - 1520-6904
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2010_Nenajdenko,
author = {Valentine G. Nenajdenko and Vasily M. Muzalevskiy and Aleksey V Shastin and Elizabeth S. Balenkova and Evgeniy V Kondrashov and Igor Ushakov and Alexander Yu. Rulev},
title = {Fragmentation of Trifluoromethylated Alkenes and Acetylenes by N,N-Binucleophiles. Synthesis of Imidazolines or Imidazolidines (Oxazolidines) Controlled by Substituent},
journal = {Journal of Organic Chemistry},
year = {2010},
volume = {75},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/jo101107t},
number = {16},
pages = {5679--5688},
doi = {10.1021/jo101107t}
}
Cite this
MLA
Copy
Nenajdenko, Valentine G., et al. “Fragmentation of Trifluoromethylated Alkenes and Acetylenes by N,N-Binucleophiles. Synthesis of Imidazolines or Imidazolidines (Oxazolidines) Controlled by Substituent.” Journal of Organic Chemistry, vol. 75, no. 16, Jul. 2010, pp. 5679-5688. https://doi.org/10.1021/jo101107t.