Pd-Catalyzed Assembly of Spirooxindole Natural Products: A Short Synthesis of Horsfiline
1
Dr. Knoell Consult GmbH, Dynamostrasse 19, 68165 Mannheim, Germany
|
3
tesa SE, Research & Development, Quickbornstrasse 24, 20253 Hamburg, Germany
|
Publication type: Journal Article
Publication date: 2010-08-05
scimago Q2
wos Q1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
20687594
Organic Chemistry
Abstract
The Pd-catalyzed intramolecular alpha-arylation of amides is applied to the synthesis of functionalized spirooxindoles. The substrate scope is evaluated, and the reaction is demonstrated to be useful for the assembly of spirooxindole natural products and derivatives thereof. As an application, a new synthesis of horsfiline 1 is presented, giving the natural product in only 4 steps from commercially available amino acid 12.
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Total citations:
83
Citations from 2024:
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(4.81%)
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GOST
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Deppermann N. et al. Pd-Catalyzed Assembly of Spirooxindole Natural Products: A Short Synthesis of Horsfiline // Journal of Organic Chemistry. 2010. Vol. 75. No. 17. pp. 5994-6000.
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Deppermann N., Thomanek H., Prenzel A. H. G. P., Maison W. Pd-Catalyzed Assembly of Spirooxindole Natural Products: A Short Synthesis of Horsfiline // Journal of Organic Chemistry. 2010. Vol. 75. No. 17. pp. 5994-6000.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/jo101401z
UR - https://doi.org/10.1021/jo101401z
TI - Pd-Catalyzed Assembly of Spirooxindole Natural Products: A Short Synthesis of Horsfiline
T2 - Journal of Organic Chemistry
AU - Deppermann, Nina
AU - Thomanek, Heike
AU - Prenzel, Alexander H G P
AU - Maison, Wolfgang
PY - 2010
DA - 2010/08/05
PB - American Chemical Society (ACS)
SP - 5994-6000
IS - 17
VL - 75
PMID - 20687594
SN - 0022-3263
SN - 1520-6904
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2010_Deppermann,
author = {Nina Deppermann and Heike Thomanek and Alexander H G P Prenzel and Wolfgang Maison},
title = {Pd-Catalyzed Assembly of Spirooxindole Natural Products: A Short Synthesis of Horsfiline},
journal = {Journal of Organic Chemistry},
year = {2010},
volume = {75},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/jo101401z},
number = {17},
pages = {5994--6000},
doi = {10.1021/jo101401z}
}
Cite this
MLA
Copy
Deppermann, Nina, et al. “Pd-Catalyzed Assembly of Spirooxindole Natural Products: A Short Synthesis of Horsfiline.” Journal of Organic Chemistry, vol. 75, no. 17, Aug. 2010, pp. 5994-6000. https://doi.org/10.1021/jo101401z.