Journal of Organic Chemistry

, том 76 , издание 8 , страницы 2548-2557

Deoxygenation of some α-dicarbonyl compounds by tris(diethylamino) phosphine in the presence of fullerene C60

Тип публикации: Journal Article

Дата публикации: 2011-03-10

American Chemical Society (ACS)

Journal of Organic Chemistry

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wos Q1

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SJR: 0.737

CiteScore: 6.1

Impact factor: 3.6

ISSN: 00223263, 15206904

DOI: 10.1021/jo102332e

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PubMed ID: 21391680

Organic Chemistry

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The reactions of such cyclic α-diketones as acenaphthenequinone, aceanthrenequinone, and N-alkylisatins, with hexaethyltriaminophosphine in the presence of the fullerene C(60), lead to the formation of methanofullerene derivatives under mild conditions. This process proceeds via deoxygenation of the dicarbonyl compound by the P(III) derivative and is likely to involve the intermediate formation of α-ketocarbenes. The structure of some methanofullerenes has been confirmed by NMR and XRD. The electrochemical behavior of the methanofullerenes was also investigated.

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Romanova I. P. et al. Deoxygenation of some α-dicarbonyl compounds by tris(diethylamino) phosphine in the presence of fullerene C60 // Journal of Organic Chemistry. 2011. Vol. 76. No. 8. pp. 2548-2557.

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Romanova I. P., Bogdanov A. V., Mironov V. L., Shaikhutdinova G. R., Larionova O. A., Latypov S., Balandina A. A., Yakhvarov D., Gubaidullin A. T., Saifina A., Sinyashin O. G. Deoxygenation of some α-dicarbonyl compounds by tris(diethylamino) phosphine in the presence of fullerene C60 // Journal of Organic Chemistry. 2011. Vol. 76. No. 8. pp. 2548-2557.

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TY - JOUR

DO - 10.1021/jo102332e

UR - https://doi.org/10.1021/jo102332e

TI - Deoxygenation of some α-dicarbonyl compounds by tris(diethylamino) phosphine in the presence of fullerene C60

T2 - Journal of Organic Chemistry

AU - Romanova, Irina P.

AU - Bogdanov, Andrey V

AU - Mironov, Valery L.

AU - Shaikhutdinova, Gulnara R

AU - Larionova, Olga A

AU - Latypov, Shamil

AU - Balandina, Alsu A

AU - Yakhvarov, Dmitry

AU - Gubaidullin, Aidar T.

AU - Saifina, Alina

AU - Sinyashin, Oleg G.

PY - 2011

DA - 2011/03/10

PB - American Chemical Society (ACS)

SP - 2548-2557

IS - 8

VL - 76

PMID - 21391680

SN - 0022-3263

SN - 1520-6904

ER -

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@article{2011_Romanova,

author = {Irina P. Romanova and Andrey V Bogdanov and Valery L. Mironov and Gulnara R Shaikhutdinova and Olga A Larionova and Shamil Latypov and Alsu A Balandina and Dmitry Yakhvarov and Aidar T. Gubaidullin and Alina Saifina and Oleg G. Sinyashin},

title = {Deoxygenation of some α-dicarbonyl compounds by tris(diethylamino) phosphine in the presence of fullerene C60},

journal = {Journal of Organic Chemistry},

year = {2011},

volume = {76},

publisher = {American Chemical Society (ACS)},

month = {mar},

url = {https://doi.org/10.1021/jo102332e},

number = {8},

pages = {2548--2557},

doi = {10.1021/jo102332e}

}

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Romanova, Irina P., et al. “Deoxygenation of some α-dicarbonyl compounds by tris(diethylamino) phosphine in the presence of fullerene C60.” Journal of Organic Chemistry, vol. 76, no. 8, Mar. 2011, pp. 2548-2557. https://doi.org/10.1021/jo102332e.