Ethyl Glyoxylate N-Tosylhydrazone as Sulfonyl-Transfer Reagent in Base-Catalyzed Sulfa-Michael Reactions
Publication type: Journal Article
Publication date: 2013-12-05
scimago Q2
wos Q1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
24286223
Organic Chemistry
Abstract
Ethyl glyoxylate N-tosylhydrazone has been identified as an excellent sulfonyl anion surrogate in the DBU-catalyzed conjugate addition reaction with enones and enals for the synthesis of functionalized sulfones. The reaction proceeds under base-catalyzed conditions and provides a direct access to γ-keto- and γ-hydroxy sulfones in a simple and reliable way through a sulfa-Michael reaction that proceeds with high yield and chemoselectivity.
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Metrics
36
Total citations:
36
Citations from 2025:
2
(5.56%)
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MLA
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GOST
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Fernandez M. et al. Ethyl Glyoxylate N-Tosylhydrazone as Sulfonyl-Transfer Reagent in Base-Catalyzed Sulfa-Michael Reactions // Journal of Organic Chemistry. 2013. Vol. 79. No. 1. pp. 441-445.
GOST all authors (up to 50)
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Fernandez M., Uria U., Orbe L., Vicario J. L., Reyes E., Carrillo L. Ethyl Glyoxylate N-Tosylhydrazone as Sulfonyl-Transfer Reagent in Base-Catalyzed Sulfa-Michael Reactions // Journal of Organic Chemistry. 2013. Vol. 79. No. 1. pp. 441-445.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/jo402518q
UR - https://doi.org/10.1021/jo402518q
TI - Ethyl Glyoxylate N-Tosylhydrazone as Sulfonyl-Transfer Reagent in Base-Catalyzed Sulfa-Michael Reactions
T2 - Journal of Organic Chemistry
AU - Fernandez, Maitane
AU - Uria, Uxue
AU - Orbe, Lucía
AU - Vicario, Jose Luis
AU - Reyes, Efraim
AU - Carrillo, Luisa
PY - 2013
DA - 2013/12/05
PB - American Chemical Society (ACS)
SP - 441-445
IS - 1
VL - 79
PMID - 24286223
SN - 0022-3263
SN - 1520-6904
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2013_Fernandez,
author = {Maitane Fernandez and Uxue Uria and Lucía Orbe and Jose Luis Vicario and Efraim Reyes and Luisa Carrillo},
title = {Ethyl Glyoxylate N-Tosylhydrazone as Sulfonyl-Transfer Reagent in Base-Catalyzed Sulfa-Michael Reactions},
journal = {Journal of Organic Chemistry},
year = {2013},
volume = {79},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/jo402518q},
number = {1},
pages = {441--445},
doi = {10.1021/jo402518q}
}
Cite this
MLA
Copy
Fernandez, Maitane, et al. “Ethyl Glyoxylate N-Tosylhydrazone as Sulfonyl-Transfer Reagent in Base-Catalyzed Sulfa-Michael Reactions.” Journal of Organic Chemistry, vol. 79, no. 1, Dec. 2013, pp. 441-445. https://doi.org/10.1021/jo402518q.