American Chemical Society (ACS)
Journal of Organic Chemistry
,  том 79 ,  издание 3 ,  страницы 1192-1198

Potassium trinitromethanide as a 1,1-ambiphilic synthon equivalent: access to 2-nitroarenofurans.

Тип публикации: Journal Article
Дата публикации: 2014-01-21
American Chemical Society (ACS)
SCImago Q2
WOS Q1
БС1
SJR: 0.604
CiteScore: 5.8
Impact factor: 3.3
ISSN: 00223263, 15206904
Organic Chemistry
Краткое описание
The first example of the use of potassium trinitromethanide as a 1,1-ambiphilic synthon equivalent for the construction of a benzofuran moiety mediated by triethylamine has been developed. The method tolerates a variety of functional groups on the starting quaternary ammonium salt and has been successfully extended to polysubstituted benzofurans. Formation of an o-quinone methide intermediate is postulated as a key to the mechanism of this cascade process.
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Osyanin V. A. et al. Potassium trinitromethanide as a 1,1-ambiphilic synthon equivalent: access to 2-nitroarenofurans. // Journal of Organic Chemistry. 2014. Vol. 79. No. 3. pp. 1192-1198.
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Osyanin V. A., Osipov D. V., Demidov M. R., Klimochkin Y. N. Potassium trinitromethanide as a 1,1-ambiphilic synthon equivalent: access to 2-nitroarenofurans. // Journal of Organic Chemistry. 2014. Vol. 79. No. 3. pp. 1192-1198.
RIS |
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TY - JOUR
DO - 10.1021/jo402543s
UR - https://doi.org/10.1021/jo402543s
TI - Potassium trinitromethanide as a 1,1-ambiphilic synthon equivalent: access to 2-nitroarenofurans.
T2 - Journal of Organic Chemistry
AU - Osyanin, Vitaly A
AU - Osipov, Dmitry V
AU - Demidov, Maxim R
AU - Klimochkin, Yuri N.
PY - 2014
DA - 2014/01/21
PB - American Chemical Society (ACS)
SP - 1192-1198
IS - 3
VL - 79
PMID - 24417319
SN - 0022-3263
SN - 1520-6904
ER -
BibTex |
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@article{2014_Osyanin,
author = {Vitaly A Osyanin and Dmitry V Osipov and Maxim R Demidov and Yuri N. Klimochkin},
title = {Potassium trinitromethanide as a 1,1-ambiphilic synthon equivalent: access to 2-nitroarenofurans.},
journal = {Journal of Organic Chemistry},
year = {2014},
volume = {79},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/jo402543s},
number = {3},
pages = {1192--1198},
doi = {10.1021/jo402543s}
}
MLA
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Osyanin, Vitaly A., et al. “Potassium trinitromethanide as a 1,1-ambiphilic synthon equivalent: access to 2-nitroarenofurans..” Journal of Organic Chemistry, vol. 79, no. 3, Jan. 2014, pp. 1192-1198. https://doi.org/10.1021/jo402543s.
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