Journal of Physical Chemistry A

, volume 106 , issue 25 , pages 6213-6222

Thiacrown ether substituted styryl dyes: Synthesis, complex formation and multiphotochromic properties

Jack Saltiel ¹

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Department of Chemistry and Biochemistry, The Florida State University, Tallahassee, Florida 32306-4390 |

Publication type: Journal Article

Publication date: 2002-06-01

American Chemical Society (ACS)

Journal of Physical Chemistry A

scimago Q2

wos Q2

SJR: 0.634

CiteScore: 4.8

Impact factor: 2.8

ISSN: 10895639, 15205215

DOI: 10.1021/jp014382m

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Physical and Theoretical Chemistry

Abstract

Syntheses of two series of new styryl dyes incorporating thiacrown ether moieties (CSDs 3a−e, 4a−e) are described. 1H NMR and UV−vis measurements show that these compounds exhibit a strong preference for formation of complexes with heavy metal ions. Polarographic measurements allow conversion of relative complex formation stability constants, determined spectrophotometrically, into absolute values. The photochromic properties of the CSDs are based on reversible trans-cis isomerization and [2+2]-photocycloaddition. The influences of the terminal group of the N-substituent and of the size and composition of the crown ether cavity on metal cation complexation selectivity and on photochromism are evaluated.

Found

3 citations

Churakov Andrei

PhD in Chemistry

554 publications, 7 046 citations, 13 reviews

h-index: 37

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

1 citation

Zubkov Fedor

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DSc in Chemistry, professor

240 publications, 3 229 citations, 19 reviews

h-index: 31

Peoples' Friendship University of Russia

Research interests

Organic Chemistry

1 citation

Pavlov Alexander

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DSc in Chemistry

120 publications, 1 969 citations

h-index: 23

Bauman Moscow State Technical University

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Mendeleev University of Chemical Technology of Russia

Research interests

Digital Chemistry

Digital Materials Science

Molecular magnetism

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Федорова О. С. et al. Thiacrown ether substituted styryl dyes: Synthesis, complex formation and multiphotochromic properties // Journal of Physical Chemistry A. 2002. Vol. 106. No. 25. pp. 6213-6222.

GOST all authors (up to 50) Copy

Saltiel J. Thiacrown ether substituted styryl dyes: Synthesis, complex formation and multiphotochromic properties // Journal of Physical Chemistry A. 2002. Vol. 106. No. 25. pp. 6213-6222.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/jp014382m

UR - https://pubs.acs.org/doi/10.1021/jp014382m

TI - Thiacrown ether substituted styryl dyes: Synthesis, complex formation and multiphotochromic properties

T2 - Journal of Physical Chemistry A

AU - Saltiel, Jack

PY - 2002

DA - 2002/06/01

PB - American Chemical Society (ACS)

SP - 6213-6222

IS - 25

VL - 106

SN - 1089-5639

SN - 1520-5215

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2002_Федорова,

author = {Jack Saltiel},

title = {Thiacrown ether substituted styryl dyes: Synthesis, complex formation and multiphotochromic properties},

journal = {Journal of Physical Chemistry A},

year = {2002},

volume = {106},

publisher = {American Chemical Society (ACS)},

month = {jun},

url = {https://pubs.acs.org/doi/10.1021/jp014382m},

number = {25},

pages = {6213--6222},

doi = {10.1021/jp014382m}

}

MLA

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MLA Copy

Федорова, О. С., et al. “Thiacrown ether substituted styryl dyes: Synthesis, complex formation and multiphotochromic properties.” Journal of Physical Chemistry A, vol. 106, no. 25, Jun. 2002, pp. 6213-6222. https://pubs.acs.org/doi/10.1021/jp014382m.