Surfactant-Encapsulated Europium-Substituted Heteropolyoxotungatate: The Structural Characterization and Photophysical Properties of Its Solid State, Solvent-Casting Film, and Langmuir−Blodgett Film
Publication type: Journal Article
Publication date: 2003-11-05
scimago Q1
wos Q3
SJR: 0.742
CiteScore: 5.3
Impact factor: 2.9
ISSN: 15206106, 15205207, 10895647
Materials Chemistry
Surfaces, Coatings and Films
Physical and Theoretical Chemistry
Abstract
The surfactant-encapsulated europium-substituted heteropolyoxotungatate, (DODA)11H2[Eu(SiW11O39)2(H2O)4] (SEC-2), is structurally characterized in detail and its photophysical behaviors are investigated. The DODA alkyl chains of SEC-2 are well ordered in the solid state, solvent-casting film, and Langmuir−Blodgett (LB) film. The europium-substituted heteropolyoxotungatate (POM-2a) is organized in the solvent-casting and LB films. A comparison of the intensities of the W−Od antisymmetrical stretching band between the infrared transmission and reflection absorption spectra of the LB films suggests that the long axis direction of POM-2a is parallel to the substrates. The solid-state SEC-2 shows two different lamellar structures with interlayer distances of 3.6 and 4.9 nm, respectively. The layer structures are well defined in both the solvent-casting and LB films and have lamellar distances of 3.6 and 4.9 nm, respectively. In short periodicities, it is considered that the alkyl chains are partially interdigi...
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Bu W. et al. Surfactant-Encapsulated Europium-Substituted Heteropolyoxotungatate: The Structural Characterization and Photophysical Properties of Its Solid State, Solvent-Casting Film, and Langmuir−Blodgett Film // Journal of Physical Chemistry B. 2003. Vol. 107. No. 48. pp. 13425-13431.
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Bu W., Wu L., Zhang X., TANG A. Surfactant-Encapsulated Europium-Substituted Heteropolyoxotungatate: The Structural Characterization and Photophysical Properties of Its Solid State, Solvent-Casting Film, and Langmuir−Blodgett Film // Journal of Physical Chemistry B. 2003. Vol. 107. No. 48. pp. 13425-13431.
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TY - JOUR
DO - 10.1021/jp0356416
UR - https://doi.org/10.1021/jp0356416
TI - Surfactant-Encapsulated Europium-Substituted Heteropolyoxotungatate: The Structural Characterization and Photophysical Properties of Its Solid State, Solvent-Casting Film, and Langmuir−Blodgett Film
T2 - Journal of Physical Chemistry B
AU - Bu, Weifeng
AU - Wu, Lixin
AU - Zhang, Xiaotao
AU - TANG, AU-CHIN
PY - 2003
DA - 2003/11/05
PB - American Chemical Society (ACS)
SP - 13425-13431
IS - 48
VL - 107
SN - 1520-6106
SN - 1520-5207
SN - 1089-5647
ER -
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@article{2003_Bu,
author = {Weifeng Bu and Lixin Wu and Xiaotao Zhang and AU-CHIN TANG},
title = {Surfactant-Encapsulated Europium-Substituted Heteropolyoxotungatate: The Structural Characterization and Photophysical Properties of Its Solid State, Solvent-Casting Film, and Langmuir−Blodgett Film},
journal = {Journal of Physical Chemistry B},
year = {2003},
volume = {107},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/jp0356416},
number = {48},
pages = {13425--13431},
doi = {10.1021/jp0356416}
}
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MLA
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Bu, Weifeng, et al. “Surfactant-Encapsulated Europium-Substituted Heteropolyoxotungatate: The Structural Characterization and Photophysical Properties of Its Solid State, Solvent-Casting Film, and Langmuir−Blodgett Film.” Journal of Physical Chemistry B, vol. 107, no. 48, Nov. 2003, pp. 13425-13431. https://doi.org/10.1021/jp0356416.