Matrix Isolation and Computational Study of the Photochemistry of 1,3,2,4-Benzodithiadiazine
Publication type: Journal Article
Publication date: 2007-01-17
scimago Q2
wos Q2
SJR: 0.634
CiteScore: 4.8
Impact factor: 2.8
ISSN: 10895639, 15205215
PubMed ID:
17266221
Physical and Theoretical Chemistry
Abstract
Photolysis of 1,3,2,4-benzodithiadiazine (1) at ambient temperature yields stable 1,2,3-benzodithiazolyl radicals. In order to reveal the mechanism of this unusual transformation, the photochemistry of 1 was studied in argon matrices using IR and UV-vis spectroscopy. A series of intermediates, including four- and five-membered heterocyclic and o-quinoid acyclic species, were characterized spectroscopically with the help of quantum chemical calculations. With selective irradiation, these intermediates can be mutually interconverted as well as converted back to the starting compound 1.
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Total citations:
19
Citations from 2024:
1
(5.26%)
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GOST
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Gritsan N. et al. Matrix Isolation and Computational Study of the Photochemistry of 1,3,2,4-Benzodithiadiazine // Journal of Physical Chemistry A. 2007. Vol. 111. No. 5. pp. 817-824.
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Gritsan N., Pritchina E. A., Bally T., Makarov A. Yu., Zibarev A. V. Matrix Isolation and Computational Study of the Photochemistry of 1,3,2,4-Benzodithiadiazine // Journal of Physical Chemistry A. 2007. Vol. 111. No. 5. pp. 817-824.
Cite this
RIS
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TY - JOUR
DO - 10.1021/jp063977k
UR - https://doi.org/10.1021/jp063977k
TI - Matrix Isolation and Computational Study of the Photochemistry of 1,3,2,4-Benzodithiadiazine
T2 - Journal of Physical Chemistry A
AU - Gritsan, N.P
AU - Pritchina, Elena A.
AU - Bally, Thomas
AU - Makarov, Alexander Yu
AU - Zibarev, Andrey V.
PY - 2007
DA - 2007/01/17
PB - American Chemical Society (ACS)
SP - 817-824
IS - 5
VL - 111
PMID - 17266221
SN - 1089-5639
SN - 1520-5215
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2007_Gritsan,
author = {N.P Gritsan and Elena A. Pritchina and Thomas Bally and Alexander Yu Makarov and Andrey V. Zibarev},
title = {Matrix Isolation and Computational Study of the Photochemistry of 1,3,2,4-Benzodithiadiazine},
journal = {Journal of Physical Chemistry A},
year = {2007},
volume = {111},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/jp063977k},
number = {5},
pages = {817--824},
doi = {10.1021/jp063977k}
}
Cite this
MLA
Copy
Gritsan, N.P, et al. “Matrix Isolation and Computational Study of the Photochemistry of 1,3,2,4-Benzodithiadiazine.” Journal of Physical Chemistry A, vol. 111, no. 5, Jan. 2007, pp. 817-824. https://doi.org/10.1021/jp063977k.