Journal of Physical Chemistry C, volume 114, issue 51, pages 22478-22486

Synthesis and Characterization of White-Emitting CdS Quantum Dots Stabilized with Polyethylenimine

Oleksandra E Rayevska 1
Galyna Ya Grodzyuk 1
O. Stroyuk 1
Stepan Ya Kuchmiy 1
Victor F. Plyusnin 1
Vyacheslav P Grivin 1
Mykhailo Ya. Valakh 1
Publication typeJournal Article
Publication date2010-12-07
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor3.7
ISSN19327447, 19327455
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
General Energy
Abstract
We report on the synthesis and optical and structural characterization of ultrasmall (<2 nm) CdS nanoparticles with a narrow size distribution of 10% prepared in aqueous and alcohol solutions of polyethyleneimine (PEI). The PEI-stabilized CdS nanoparticles reveal a structured absorption band with the first excitonic maximum at 3.5 eV and broad-band photoluminescence with quantum yields of 12−14% in water, 18−20% in ethanol (80 vol %), and up to 60−70% in solid PEI films at room temperature. The nature of the photoluminescence was studied by using the time- and wavelength-dependent emission measurements. The role of precursor cadmium(II)−PEI complex in the formation of uniform and ultrasmall luminescent CdS nanoparticles, as well as the dynamic emission quenching by water, are discussed. A study of the photochemical properties of PEI-stabilized CdS nanoparticles both under continuous and nanosecond pulse illumination showed excellent stability of solid PEI films incorporating CdS nanoparticles toward UV il...

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Rayevska O. E. et al. Synthesis and Characterization of White-Emitting CdS Quantum Dots Stabilized with Polyethylenimine // Journal of Physical Chemistry C. 2010. Vol. 114. No. 51. pp. 22478-22486.
GOST all authors (up to 50) Copy
Rayevska O. E., Grodzyuk G. Ya., Zahn D. R. T., Stroyuk O., Kuchmiy S. Ya., Plyusnin V. F., Grivin V. P., Valakh M. Y. Synthesis and Characterization of White-Emitting CdS Quantum Dots Stabilized with Polyethylenimine // Journal of Physical Chemistry C. 2010. Vol. 114. No. 51. pp. 22478-22486.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/jp108561u
UR - https://doi.org/10.1021/jp108561u
TI - Synthesis and Characterization of White-Emitting CdS Quantum Dots Stabilized with Polyethylenimine
T2 - Journal of Physical Chemistry C
AU - Rayevska, Oleksandra E
AU - Grodzyuk, Galyna Ya
AU - Kuchmiy, Stepan Ya
AU - Plyusnin, Victor F.
AU - Grivin, Vyacheslav P
AU - Zahn, Dietrich R. T.
AU - Stroyuk, O.
AU - Valakh, Mykhailo Ya.
PY - 2010
DA - 2010/12/07 00:00:00
PB - American Chemical Society (ACS)
SP - 22478-22486
IS - 51
VL - 114
SN - 1932-7447
SN - 1932-7455
ER -
BibTex |
Cite this
BibTex Copy
@article{2010_Rayevska,
author = {Oleksandra E Rayevska and Galyna Ya Grodzyuk and Stepan Ya Kuchmiy and Victor F. Plyusnin and Vyacheslav P Grivin and Dietrich R. T. Zahn and O. Stroyuk and Mykhailo Ya. Valakh},
title = {Synthesis and Characterization of White-Emitting CdS Quantum Dots Stabilized with Polyethylenimine},
journal = {Journal of Physical Chemistry C},
year = {2010},
volume = {114},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/jp108561u},
number = {51},
pages = {22478--22486},
doi = {10.1021/jp108561u}
}
MLA
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MLA Copy
Rayevska, Oleksandra E., et al. “Synthesis and Characterization of White-Emitting CdS Quantum Dots Stabilized with Polyethylenimine.” Journal of Physical Chemistry C, vol. 114, no. 51, Dec. 2010, pp. 22478-22486. https://doi.org/10.1021/jp108561u.
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