Structure and Dynamics of P,N-Containing Heterocycles and Their Metal Complexes in Solution
Shamil Latypov
1
,
Anna G Strelnik
1
,
Svetlana N Ignatieva
1
,
Anna Balueva
1
,
Andrey A Karasik
1
,
Publication type: Journal Article
Publication date: 2012-03-13
scimago Q2
wos Q2
SJR: 0.634
CiteScore: 4.8
Impact factor: 2.8
ISSN: 10895639, 15205215
PubMed ID:
22414208
Physical and Theoretical Chemistry
Abstract
Conformations and dynamics of 1,5-diaza-3,7-diphosphacyclooctane (1) with chiral l-menthyl substituents on the phosphorus atoms and several metal complexes thereof were investigated by a variety of DNMR methods. In solution 1 adopts a C(2) symmetrical "crown"-like conformation (CW) and the conformational preference and dynamics of the complexes depend on the type of metal: for the Cu complex the CW form is preferred, whereas the Pd, Pt, or Mo complexes exist in an equilibrium of two "chair-boat"-like conformations (CB/CB*). The barriers of interconversion between these two conformations for the Pd and Pt complexes are about 2 times higher than for the Mo complex. Quantum chemical calculations (B3LYP/6-31G(d)) are in agreement with experimental findings.
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27
Total citations:
27
Citations from 2024:
3
(11.11%)
The most citing journal
Citations in journal:
4
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GOST
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Latypov S. et al. Structure and Dynamics of P,N-Containing Heterocycles and Their Metal Complexes in Solution // Journal of Physical Chemistry A. 2012. Vol. 116. No. 12. pp. 3182-3193.
GOST all authors (up to 50)
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Latypov S., Strelnik A. G., Ignatieva S. N., Hey-Hawkins E., Balueva A., Karasik A. A., Sinyashin O. G. Structure and Dynamics of P,N-Containing Heterocycles and Their Metal Complexes in Solution // Journal of Physical Chemistry A. 2012. Vol. 116. No. 12. pp. 3182-3193.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/jp209281c
UR - https://doi.org/10.1021/jp209281c
TI - Structure and Dynamics of P,N-Containing Heterocycles and Their Metal Complexes in Solution
T2 - Journal of Physical Chemistry A
AU - Latypov, Shamil
AU - Strelnik, Anna G
AU - Ignatieva, Svetlana N
AU - Hey-Hawkins, Evamarie
AU - Balueva, Anna
AU - Karasik, Andrey A
AU - Sinyashin, Oleg G.
PY - 2012
DA - 2012/03/13
PB - American Chemical Society (ACS)
SP - 3182-3193
IS - 12
VL - 116
PMID - 22414208
SN - 1089-5639
SN - 1520-5215
ER -
Cite this
BibTex (up to 50 authors)
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@article{2012_Latypov,
author = {Shamil Latypov and Anna G Strelnik and Svetlana N Ignatieva and Evamarie Hey-Hawkins and Anna Balueva and Andrey A Karasik and Oleg G. Sinyashin},
title = {Structure and Dynamics of P,N-Containing Heterocycles and Their Metal Complexes in Solution},
journal = {Journal of Physical Chemistry A},
year = {2012},
volume = {116},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/jp209281c},
number = {12},
pages = {3182--3193},
doi = {10.1021/jp209281c}
}
Cite this
MLA
Copy
Latypov, Shamil, et al. “Structure and Dynamics of P,N-Containing Heterocycles and Their Metal Complexes in Solution.” Journal of Physical Chemistry A, vol. 116, no. 12, Mar. 2012, pp. 3182-3193. https://doi.org/10.1021/jp209281c.
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