Synthesis and Spectroscopic Properties of Monoclinic α-Eu2(MoO4)3
5
Publication type: Journal Article
Publication date: 2014-07-08
scimago Q1
wos Q3
SJR: 0.914
CiteScore: 6.2
Impact factor: 3.2
ISSN: 19327447, 19327455
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
General Energy
Abstract
The microcrystals of monoclinic europium molybdate, α-Eu2(MoO4)3, have been fabricated by solid-state synthesis at T = 753–1273 K for 300 h. The crystal structure of α-Eu2(MoO4)3 has been refined by the Rietveld method and was found to belong to the space group C2/c with unit cell parameters a = 7.5576(1), b = 11.4709(2), c = 11.5158(2) A, and β = 109.278(1)° (RB = 3.39%). About 40 narrow Raman lines have been observed in the Raman spectrum of the α-Eu2(MoO4)3 powder sample. The luminescence spectra of α-Eu2(MoO4)3 under excitation at 355 and 457.9 nm reveal domination of induced electric dipole transition 5D0 → 7F2 and the presence of ultranarrow lines at 5D0 → 7F0 and 5D1 → 7F0 transitions.
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Atuchin V. V. et al. Synthesis and Spectroscopic Properties of Monoclinic α-Eu2(MoO4)3 // Journal of Physical Chemistry C. 2014. Vol. 118. No. 28. pp. 15404-15411.
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Atuchin V. V., Aleksandrovsky A., Chimitova O. D., Gavrilova T., Krylov A. A., Molokeev M. S., Oreshonkov A. S., Bazarov B. G., Bazarova J. Synthesis and Spectroscopic Properties of Monoclinic α-Eu2(MoO4)3 // Journal of Physical Chemistry C. 2014. Vol. 118. No. 28. pp. 15404-15411.
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TY - JOUR
DO - 10.1021/jp5040739
UR - https://doi.org/10.1021/jp5040739
TI - Synthesis and Spectroscopic Properties of Monoclinic α-Eu2(MoO4)3
T2 - Journal of Physical Chemistry C
AU - Atuchin, V. V.
AU - Aleksandrovsky, Aleksandr
AU - Chimitova, O D
AU - Gavrilova, T.A.
AU - Krylov, A. A.
AU - Molokeev, Maxim S.
AU - Oreshonkov, Aleksandr S.
AU - Bazarov, B G
AU - Bazarova, Jibzema
PY - 2014
DA - 2014/07/08
PB - American Chemical Society (ACS)
SP - 15404-15411
IS - 28
VL - 118
SN - 1932-7447
SN - 1932-7455
ER -
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@article{2014_Atuchin,
author = {V. V. Atuchin and Aleksandr Aleksandrovsky and O D Chimitova and T.A. Gavrilova and A. A. Krylov and Maxim S. Molokeev and Aleksandr S. Oreshonkov and B G Bazarov and Jibzema Bazarova},
title = {Synthesis and Spectroscopic Properties of Monoclinic α-Eu2(MoO4)3},
journal = {Journal of Physical Chemistry C},
year = {2014},
volume = {118},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/jp5040739},
number = {28},
pages = {15404--15411},
doi = {10.1021/jp5040739}
}
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MLA
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Atuchin, V. V., et al. “Synthesis and Spectroscopic Properties of Monoclinic α-Eu2(MoO4)3.” Journal of Physical Chemistry C, vol. 118, no. 28, Jul. 2014, pp. 15404-15411. https://doi.org/10.1021/jp5040739.