Platelike LiMPO4 (M = Fe, Mn, Co, Ni) for Possible Application in Rechargeable Li Ion Batteries: Beyond Nanosize
Publication type: Journal Article
Publication date: 2014-07-28
scimago Q1
wos Q3
SJR: 0.914
CiteScore: 6.2
Impact factor: 3.2
ISSN: 19327447, 19327455
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
General Energy
Abstract
The peculiarities of LiMPO4 (M = Fe, Mn, Co, Ni) formation with controlled platelike crystal shape using layered M(OH)2 hydroxides as templates were studied. Thin, platelike crystals of NH4MPO4·H2O with Mn, Fe, and Co were formed in aqueous solutions as intermediate products, whereas for NH4NiPO4·6H2O, particles in the form of spherulites were observed. For replacement of ammonium groups by lithium cations, a solid-state reaction between NH4MPO4·xH2O and Li2CO3 at elevated temperatures was used. The obtained LiMPO4 particles repeat completely the shape of the intermediated NH4MPO4·xH2O crystals. The surface of platelike particles represents a cellular structure and consists of agglomerated, slightly randomized crystallites of several hundred nanometers, which are oriented along the c-axis perpendicular to the plate surface. It was shown in the LiFePO4 example that the cathode materials, consisting of platelike particles and reduced graphene oxide (RGO), have the discharge capacity of 145 mAh/g in Li ion b...
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Alyoshin V. A. et al. Platelike LiMPO4 (M = Fe, Mn, Co, Ni) for Possible Application in Rechargeable Li Ion Batteries: Beyond Nanosize // Journal of Physical Chemistry C. 2014. Vol. 118. No. 31. pp. 17426-17435.
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Alyoshin V. A., Pleshakov E. A., Ehrenberg H., Mikhailova D. Platelike LiMPO4 (M = Fe, Mn, Co, Ni) for Possible Application in Rechargeable Li Ion Batteries: Beyond Nanosize // Journal of Physical Chemistry C. 2014. Vol. 118. No. 31. pp. 17426-17435.
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TY - JOUR
DO - 10.1021/jp504587f
UR - https://doi.org/10.1021/jp504587f
TI - Platelike LiMPO4 (M = Fe, Mn, Co, Ni) for Possible Application in Rechargeable Li Ion Batteries: Beyond Nanosize
T2 - Journal of Physical Chemistry C
AU - Alyoshin, V. A.
AU - Pleshakov, E A
AU - Ehrenberg, H.
AU - Mikhailova, D.
PY - 2014
DA - 2014/07/28
PB - American Chemical Society (ACS)
SP - 17426-17435
IS - 31
VL - 118
SN - 1932-7447
SN - 1932-7455
ER -
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BibTex (up to 50 authors)
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@article{2014_Alyoshin,
author = {V. A. Alyoshin and E A Pleshakov and H. Ehrenberg and D. Mikhailova},
title = {Platelike LiMPO4 (M = Fe, Mn, Co, Ni) for Possible Application in Rechargeable Li Ion Batteries: Beyond Nanosize},
journal = {Journal of Physical Chemistry C},
year = {2014},
volume = {118},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/jp504587f},
number = {31},
pages = {17426--17435},
doi = {10.1021/jp504587f}
}
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MLA
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Alyoshin, V. A., et al. “Platelike LiMPO4 (M = Fe, Mn, Co, Ni) for Possible Application in Rechargeable Li Ion Batteries: Beyond Nanosize.” Journal of Physical Chemistry C, vol. 118, no. 31, Jul. 2014, pp. 17426-17435. https://doi.org/10.1021/jp504587f.