Journal of Physical Chemistry C, volume 118, issue 38, pages 21834-21845
Symmetry-Breaking Charge Transfer of Visible Light Absorbing Systems: Zinc Dipyrrins
Publication type: Journal Article
Publication date: 2014-09-11
Journal:
Journal of Physical Chemistry C
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 3.7
ISSN: 19327447, 19327455
PubMed ID:
25270268
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
General Energy
Abstract
Zinc dipyrrin complexes with two identical dipyrrin ligands absorb strongly at 450–550 nm and exhibit high fluorescence quantum yields in nonpolar solvents (e.g., 0.16–0.66 in cyclohexane) and weak to nonexistent emission in polar solvents (i.e., <10–3, in acetonitrile). The low quantum efficiencies in polar solvents are attributed to the formation of a nonemissive symmetry-breaking charge transfer (SBCT) state, which is not formed in nonpolar solvents. Analysis using ultrafast spectroscopy shows that in polar solvents the singlet excited state relaxes to the SBCT state in 1.0–5.5 ps and then decays via recombination to the triplet or ground states in 0.9–3.3 ns. In the weakly polar solvent toluene, the equilibrium between a localized excited state and the charge transfer state is established in 11–22 ps.
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Cong T. et al. Symmetry-Breaking Charge Transfer of Visible Light Absorbing Systems: Zinc Dipyrrins // Journal of Physical Chemistry C. 2014. Vol. 118. No. 38. pp. 21834-21845.
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Cong T., Kirlikovali K., Das S., Ener M. E., Gray H. B., Djurovich P. I., Bradforth S. E., Thompson M. E. Symmetry-Breaking Charge Transfer of Visible Light Absorbing Systems: Zinc Dipyrrins // Journal of Physical Chemistry C. 2014. Vol. 118. No. 38. pp. 21834-21845.
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TY - JOUR
DO - 10.1021/jp506855t
UR - https://doi.org/10.1021%2Fjp506855t
TI - Symmetry-Breaking Charge Transfer of Visible Light Absorbing Systems: Zinc Dipyrrins
T2 - Journal of Physical Chemistry C
AU - Cong, Trinh
AU - Kirlikovali, Kent
AU - Ener, Maraia E
AU - Das, Saptaparna
AU - Gray, Harry B.
AU - Djurovich, Peter I.
AU - Bradforth, Stephen E.
AU - Thompson, Mark E
PY - 2014
DA - 2014/09/11 00:00:00
PB - American Chemical Society (ACS)
SP - 21834-21845
IS - 38
VL - 118
PMID - 25270268
SN - 1932-7447
SN - 1932-7455
ER -
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@article{2014_Cong,
author = {Trinh Cong and Kent Kirlikovali and Maraia E Ener and Saptaparna Das and Harry B. Gray and Peter I. Djurovich and Stephen E. Bradforth and Mark E Thompson},
title = {Symmetry-Breaking Charge Transfer of Visible Light Absorbing Systems: Zinc Dipyrrins},
journal = {Journal of Physical Chemistry C},
year = {2014},
volume = {118},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021%2Fjp506855t},
number = {38},
pages = {21834--21845},
doi = {10.1021/jp506855t}
}
Cite this
MLA
Copy
Cong, Trinh, et al. “Symmetry-Breaking Charge Transfer of Visible Light Absorbing Systems: Zinc Dipyrrins.” Journal of Physical Chemistry C, vol. 118, no. 38, Sep. 2014, pp. 21834-21845. https://doi.org/10.1021%2Fjp506855t.