volume 118 issue 41 pages 23835-23844

Reasons for the Differences in the Kinetics of Thermal Oxidation of the Support in Pt/C Electrocatalysts

Publication typeJournal Article
Publication date2014-10-06
scimago Q1
wos Q3
SJR0.914
CiteScore6.2
Impact factor3.2
ISSN19327447, 19327455
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
General Energy
Abstract
High-temperature oxidation processes of carbon microparticles Vulcan XC72 coated with platinum nanoparticles (Pt/C) were studied by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The presence of different specific temperature ranges in the oxidation of carbon support was shown to be due to both the peculiarities of granulometric composition of carbon black microparticles, different size, and uneven spatial distribution of platinum nanoparticles in the pores and on the surface of the carbon support. The correlation between the length of a section in the thermograms and the fraction of carbon microparticles poorly coated with platinum can be used to analyze the uniformity of Pt nanoparticle spatial distribution in the metal–carbon catalysts and therefore to select electrocatalysts with optimal microstructure. This analysis is expected to be effectively utilized in order to assess the uniformity of platinum distribution on carbon microparticles and also to provide additional in...
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GOST Copy
Guterman V. E. et al. Reasons for the Differences in the Kinetics of Thermal Oxidation of the Support in Pt/C Electrocatalysts // Journal of Physical Chemistry C. 2014. Vol. 118. No. 41. pp. 23835-23844.
GOST all authors (up to 50) Copy
Guterman V. E., Belenov S., Krikov V. V., Vysochina L. L., Yohannes W., Tabachkova N. Yu., Balakshina E. N. Reasons for the Differences in the Kinetics of Thermal Oxidation of the Support in Pt/C Electrocatalysts // Journal of Physical Chemistry C. 2014. Vol. 118. No. 41. pp. 23835-23844.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/jp507801f
UR - https://doi.org/10.1021/jp507801f
TI - Reasons for the Differences in the Kinetics of Thermal Oxidation of the Support in Pt/C Electrocatalysts
T2 - Journal of Physical Chemistry C
AU - Guterman, V. E.
AU - Belenov, Sergey
AU - Krikov, Vladimir V
AU - Vysochina, Larisa L
AU - Yohannes, Weldegebriel
AU - Tabachkova, Natalya Yu
AU - Balakshina, Elena N
PY - 2014
DA - 2014/10/06
PB - American Chemical Society (ACS)
SP - 23835-23844
IS - 41
VL - 118
SN - 1932-7447
SN - 1932-7455
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2014_Guterman,
author = {V. E. Guterman and Sergey Belenov and Vladimir V Krikov and Larisa L Vysochina and Weldegebriel Yohannes and Natalya Yu Tabachkova and Elena N Balakshina},
title = {Reasons for the Differences in the Kinetics of Thermal Oxidation of the Support in Pt/C Electrocatalysts},
journal = {Journal of Physical Chemistry C},
year = {2014},
volume = {118},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/jp507801f},
number = {41},
pages = {23835--23844},
doi = {10.1021/jp507801f}
}
MLA
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MLA Copy
Guterman, V. E., et al. “Reasons for the Differences in the Kinetics of Thermal Oxidation of the Support in Pt/C Electrocatalysts.” Journal of Physical Chemistry C, vol. 118, no. 41, Oct. 2014, pp. 23835-23844. https://doi.org/10.1021/jp507801f.