volume 103 issue 31 pages 6498-6503

Nitrogen and Argon Adsorption and SEM Characterization of C60 and C60/C70 Fullerenes:  Comparison with Graphite

Vladimir Yu Gusev 1
Sigrid Ruetsch 1
Ludwig A Popeko 1
Ilya E Popeko 1
1
 
TRI/Princeton, P.O. Box 625, Princeton, New Jersey 08542, Neutrino Physics Laboratory, St. Petersburg Institute of Nuclear Physics, Gatchina, St. Petersburg District, 188350, Russia, and Semi-Alloys Company, 888 South Columbus Avenue, Mount Vernon, New York 10550
Publication typeJournal Article
Publication date1999-07-14
scimago Q1
wos Q3
SJR0.742
CiteScore5.3
Impact factor2.9
ISSN15206106, 15205207, 10895647
Materials Chemistry
Surfaces, Coatings and Films
Physical and Theoretical Chemistry
Abstract
The surface and pore structure properties of the C60 and C60/C70 fullerene powders were studied by means of scanning electron microscopy, helium pycnometry, and 77.4 K nitrogen and argon adsorption. The pore structure of fullerene powders is macroporous and consists mainly of the voids between the fullerene aggregates. In the major part of the adsorption monolayer, both nitrogen and argon interactions with fullerenes are weaker than with graphite, possibly because of the reduction of the gas molecule−mirror image effect in the case of fullerenes. In Henry's law limit, however, nitrogen and argon adsorption on fullerenes is quantitatively similar to that on graphite because of the adsorption potential enhancement in the spaces between the surface fullerene molecules. In the multilayer regime, nitrogen adsorption on both fullerenes becomes similar to that on graphite. Both fullerenes behave similarly with respect to the adsorption of the studied gases.
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Gusev V. Yu. et al. Nitrogen and Argon Adsorption and SEM Characterization of C60 and C60/C70 Fullerenes: Comparison with Graphite // Journal of Physical Chemistry B. 1999. Vol. 103. No. 31. pp. 6498-6503.
GOST all authors (up to 50) Copy
Gusev V. Yu., Ruetsch S., Popeko L. A., Popeko I. E. Nitrogen and Argon Adsorption and SEM Characterization of C60 and C60/C70 Fullerenes: Comparison with Graphite // Journal of Physical Chemistry B. 1999. Vol. 103. No. 31. pp. 6498-6503.
RIS |
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TY - JOUR
DO - 10.1021/jp991081s
UR - https://doi.org/10.1021/jp991081s
TI - Nitrogen and Argon Adsorption and SEM Characterization of C60 and C60/C70 Fullerenes: Comparison with Graphite
T2 - Journal of Physical Chemistry B
AU - Gusev, Vladimir Yu
AU - Ruetsch, Sigrid
AU - Popeko, Ludwig A
AU - Popeko, Ilya E
PY - 1999
DA - 1999/07/14
PB - American Chemical Society (ACS)
SP - 6498-6503
IS - 31
VL - 103
SN - 1520-6106
SN - 1520-5207
SN - 1089-5647
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{1999_Gusev,
author = {Vladimir Yu Gusev and Sigrid Ruetsch and Ludwig A Popeko and Ilya E Popeko},
title = {Nitrogen and Argon Adsorption and SEM Characterization of C60 and C60/C70 Fullerenes: Comparison with Graphite},
journal = {Journal of Physical Chemistry B},
year = {1999},
volume = {103},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/jp991081s},
number = {31},
pages = {6498--6503},
doi = {10.1021/jp991081s}
}
MLA
Cite this
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Gusev, Vladimir Yu., et al. “Nitrogen and Argon Adsorption and SEM Characterization of C60 and C60/C70 Fullerenes: Comparison with Graphite.” Journal of Physical Chemistry B, vol. 103, no. 31, Jul. 1999, pp. 6498-6503. https://doi.org/10.1021/jp991081s.