том 26 издание 3 страницы 424-428

Living carbocationic polymerization. 55. Living polymerization of indene

Тип публикацииJournal Article
Дата публикации1993-02-01
scimago Q1
wos Q1
БС1
SJR1.352
CiteScore9
Impact factor5.2
ISSN00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Краткое описание
The cationic polymerization of indene (In) has been investigated using the 2-chloro-2,4,4- trimethylpentane (TMPCl)/TiCl 4 initiating system and a methyl chloride-methylcyclohexane solvent mixture at -80°C. According to kinetic studies, initiation is slow relative to propagation. The quantitative treatment of slow initiation in living cationic polymerization applied to this system led to the conclusion that this polymerization is living and the rate-determining step is cationation. The end-groups of polyindene are secondary chlorines.
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ГОСТ |
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Kennedy J. W., Midha S., Keszler B. Living carbocationic polymerization. 55. Living polymerization of indene // Macromolecules. 1993. Vol. 26. No. 3. pp. 424-428.
ГОСТ со всеми авторами (до 50) Скопировать
Kennedy J. W., Midha S., Keszler B. Living carbocationic polymerization. 55. Living polymerization of indene // Macromolecules. 1993. Vol. 26. No. 3. pp. 424-428.
RIS |
Цитировать
TY - JOUR
DO - 10.1021/ma00055a003
UR - https://doi.org/10.1021/ma00055a003
TI - Living carbocationic polymerization. 55. Living polymerization of indene
T2 - Macromolecules
AU - Kennedy, Joseph W.
AU - Midha, Sanjeev
AU - Keszler, Balazs
PY - 1993
DA - 1993/02/01
PB - American Chemical Society (ACS)
SP - 424-428
IS - 3
VL - 26
SN - 0024-9297
SN - 1520-5835
ER -
BibTex |
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BibTex (до 50 авторов) Скопировать
@article{1993_Kennedy,
author = {Joseph W. Kennedy and Sanjeev Midha and Balazs Keszler},
title = {Living carbocationic polymerization. 55. Living polymerization of indene},
journal = {Macromolecules},
year = {1993},
volume = {26},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/ma00055a003},
number = {3},
pages = {424--428},
doi = {10.1021/ma00055a003}
}
MLA
Цитировать
Kennedy, Joseph W., et al. “Living carbocationic polymerization. 55. Living polymerization of indene.” Macromolecules, vol. 26, no. 3, Feb. 1993, pp. 424-428. https://doi.org/10.1021/ma00055a003.