Relaxation and viscosity anomaly of melts made of long entangled polymers: time-dependent reptation
Тип публикации: Journal Article
Дата публикации: 1990-10-01
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 1.257
CiteScore: 8.8
Impact factor: 5.7
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Краткое описание
The stress relaxation function, G(t) (t=time), of a melt made of long entangled polymers is calculated by applying a modified version of the reptation concept introduced by de Gennes. For blends made of polydisperse polymers belonging to the same species, G(t) is calculated in the same way, by direct application of the double reptation principle. The theoretical results are in rather good agreement with experimental data obtained by Colby for polybutadiene. A simpler semiphenomenological diffusion equation is also studied and its leads to fairly similar results. The viscosity associated with G(t) is calculated
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141
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141
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ГОСТ
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des Cloizeaux J. Relaxation and viscosity anomaly of melts made of long entangled polymers: time-dependent reptation // Macromolecules. 1990. Vol. 23. No. 21. pp. 4678-4687.
ГОСТ со всеми авторами (до 50)
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des Cloizeaux J. Relaxation and viscosity anomaly of melts made of long entangled polymers: time-dependent reptation // Macromolecules. 1990. Vol. 23. No. 21. pp. 4678-4687.
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RIS
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TY - JOUR
DO - 10.1021/ma00223a028
UR - https://doi.org/10.1021/ma00223a028
TI - Relaxation and viscosity anomaly of melts made of long entangled polymers: time-dependent reptation
T2 - Macromolecules
AU - des Cloizeaux, J.
PY - 1990
DA - 1990/10/01
PB - American Chemical Society (ACS)
SP - 4678-4687
IS - 21
VL - 23
SN - 0024-9297
SN - 1520-5835
ER -
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BibTex (до 50 авторов)
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@article{1990_des Cloizeaux,
author = {J. des Cloizeaux},
title = {Relaxation and viscosity anomaly of melts made of long entangled polymers: time-dependent reptation},
journal = {Macromolecules},
year = {1990},
volume = {23},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/ma00223a028},
number = {21},
pages = {4678--4687},
doi = {10.1021/ma00223a028}
}
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MLA
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des Cloizeaux, J.. “Relaxation and viscosity anomaly of melts made of long entangled polymers: time-dependent reptation.” Macromolecules, vol. 23, no. 21, Oct. 1990, pp. 4678-4687. https://doi.org/10.1021/ma00223a028.
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