Macromolecules, volume 35, issue 8, pages 3213-3224
Healing of Thermoplastic Polymers at an Interface under Nonisothermal Conditions
1
Composites Processing Laboratory, Department of Mechanical Engineering, University of Connecticut, Storrs, Connecticut 06269-3139
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Publication type: Journal Article
Publication date: 2002-03-15
Journal:
Macromolecules
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.5
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
Fabrication of layered thermoplastic polymer products involves applying heat and pressure to contacting thermoplastic surfaces and consolidating the interface. Polymer healing, referring to the intermolecular diffusion across the interfaces of thermoplastic tape layers in intimate contact, is one of the important steps responsible for the development of interlaminar bond strength and is strongly influenced by the temperature history. While the theory for healing under isothermal conditions is well established in the literature, the available descriptions of healing under nonisothermal processing conditions lack a sound fundamental basis. In this paper, a model for the healing process under nonisothermal conditions is developed starting from a fundamental formulation of the reptation of polymer chains. Considering the temperature dependence of the welding time, the bond strength is described as a function of temperature history. It is shown that, under certain nonisothermal conditions, considerable errors ...
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GOST
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Yang F., Pitchumani R. Healing of Thermoplastic Polymers at an Interface under Nonisothermal Conditions // Macromolecules. 2002. Vol. 35. No. 8. pp. 3213-3224.
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Yang F., Pitchumani R. Healing of Thermoplastic Polymers at an Interface under Nonisothermal Conditions // Macromolecules. 2002. Vol. 35. No. 8. pp. 3213-3224.
Cite this
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TY - JOUR
DO - 10.1021/ma010858o
UR - https://doi.org/10.1021/ma010858o
TI - Healing of Thermoplastic Polymers at an Interface under Nonisothermal Conditions
T2 - Macromolecules
AU - Yang, F.
AU - Pitchumani, R.
PY - 2002
DA - 2002/03/15
PB - American Chemical Society (ACS)
SP - 3213-3224
IS - 8
VL - 35
SN - 0024-9297
SN - 1520-5835
ER -
Cite this
BibTex
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@article{2002_Yang,
author = {F. Yang and R. Pitchumani},
title = {Healing of Thermoplastic Polymers at an Interface under Nonisothermal Conditions},
journal = {Macromolecules},
year = {2002},
volume = {35},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/ma010858o},
number = {8},
pages = {3213--3224},
doi = {10.1021/ma010858o}
}
Cite this
MLA
Copy
Yang, F., and R. Pitchumani. “Healing of Thermoplastic Polymers at an Interface under Nonisothermal Conditions.” Macromolecules, vol. 35, no. 8, Mar. 2002, pp. 3213-3224. https://doi.org/10.1021/ma010858o.