Controlled Nitroxide-Mediated Radical Polymerization of Styrene, Styrene/Acrylonitrile Mixtures, and Dienes Using a Nitrone
Publication type: Journal Article
Publication date: 2002-08-16
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
Radical polymerization of styrene and copolymerization of styrene and acrylonitrile (60/40) are controlled when conducted in the presence of N-tert-butyl-α-isopropylnitrone, which is easily synthesized from cheap reagents. However, for the control to be effective, the nitrone has to be prereacted with the radical initiator. Nitroxides are then formed “in situ”, such that this nitrone system is an attractive alternative for the classical nitroxide-mediated polymerization (NMP), which may require a multistep synthesis of nitroxides or alkoxyamines. The choice of the radical initiator is important because it dictates the structure of the nitroxide and thus its capacity to control the radical polymerization. Well-defined poly(styrene)-b-poly(styrene-co-acrylonitrile), poly(styrene)-b-poly(n-butyl acrylate), and poly(styrene)-b-poly(isoprene) copolymers have been successfully synthesized by this process.
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Metrics
60
Total citations:
60
Citations from 2024:
2
(3.34%)
The most citing journal
Citations in journal:
6
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MLA
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GOST
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Detrembleur C. et al. Controlled Nitroxide-Mediated Radical Polymerization of Styrene, Styrene/Acrylonitrile Mixtures, and Dienes Using a Nitrone // Macromolecules. 2002. Vol. 35. No. 19. pp. 7214-7223.
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Detrembleur C., Sciannamea V., Koulic C., Claes M., Hoebeke M., Jerome R. Controlled Nitroxide-Mediated Radical Polymerization of Styrene, Styrene/Acrylonitrile Mixtures, and Dienes Using a Nitrone // Macromolecules. 2002. Vol. 35. No. 19. pp. 7214-7223.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ma0201835
UR - https://doi.org/10.1021/ma0201835
TI - Controlled Nitroxide-Mediated Radical Polymerization of Styrene, Styrene/Acrylonitrile Mixtures, and Dienes Using a Nitrone
T2 - Macromolecules
AU - Detrembleur, Christophe
AU - Sciannamea, V
AU - Koulic, C
AU - Claes, M.
AU - Hoebeke, M
AU - Jerome, R.
PY - 2002
DA - 2002/08/16
PB - American Chemical Society (ACS)
SP - 7214-7223
IS - 19
VL - 35
SN - 0024-9297
SN - 1520-5835
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2002_Detrembleur,
author = {Christophe Detrembleur and V Sciannamea and C Koulic and M. Claes and M Hoebeke and R. Jerome},
title = {Controlled Nitroxide-Mediated Radical Polymerization of Styrene, Styrene/Acrylonitrile Mixtures, and Dienes Using a Nitrone},
journal = {Macromolecules},
year = {2002},
volume = {35},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/ma0201835},
number = {19},
pages = {7214--7223},
doi = {10.1021/ma0201835}
}
Cite this
MLA
Copy
Detrembleur, Christophe, et al. “Controlled Nitroxide-Mediated Radical Polymerization of Styrene, Styrene/Acrylonitrile Mixtures, and Dienes Using a Nitrone.” Macromolecules, vol. 35, no. 19, Aug. 2002, pp. 7214-7223. https://doi.org/10.1021/ma0201835.