Preparation of Linear and Star-Shaped Block Copolymers by ATRP Using Simultaneous Reverse and Normal Initiation Process in Bulk and Miniemulsion
Publication type: Journal Article
Publication date: 2004-03-02
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
Well-defined linear and star-shaped block copolymers were synthesized using halogenated ATRP macroinitiator via a simultaneous reverse and normal initiation (SRN Mw/Mn = 1.08) was extended with styrene to form star-shaped block copolymer, poly(methyl acrylate)-b-polystyrene, with Mn = 24 700 g/mol and Mw/Mn = 1.41 in bulk condition (yield = 72%) and Mn = 22 100 g/mol and Mw/Mn = 1.37 in miniemulsion (yield = 72%). This newly developed ATRP process requires a significantly reduced amount of highly active ATRP catalyst complex in its oxidatively stable high oxidation state (e.g., CuIIBr2/ligand), while the predominant initiating species was a normal halogen-containing macroinitiator. The compositiona...
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Metrics
145
Total citations:
145
Citations from 2024:
6
(4.14%)
The most citing journal
Citations in journal:
19
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MLA
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GOST
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Li M. et al. Preparation of Linear and Star-Shaped Block Copolymers by ATRP Using Simultaneous Reverse and Normal Initiation Process in Bulk and Miniemulsion // Macromolecules. 2004. Vol. 37. No. 7. pp. 2434-2441.
GOST all authors (up to 50)
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Li M., Jahed N., Ke M., Matyjaszewski K. Preparation of Linear and Star-Shaped Block Copolymers by ATRP Using Simultaneous Reverse and Normal Initiation Process in Bulk and Miniemulsion // Macromolecules. 2004. Vol. 37. No. 7. pp. 2434-2441.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ma035712z
UR - https://doi.org/10.1021/ma035712z
TI - Preparation of Linear and Star-Shaped Block Copolymers by ATRP Using Simultaneous Reverse and Normal Initiation Process in Bulk and Miniemulsion
T2 - Macromolecules
AU - Li, Mei
AU - Jahed, Nazeem
AU - Ke, Min
AU - Matyjaszewski, Krzysztof
PY - 2004
DA - 2004/03/02
PB - American Chemical Society (ACS)
SP - 2434-2441
IS - 7
VL - 37
SN - 0024-9297
SN - 1520-5835
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2004_Li,
author = {Mei Li and Nazeem Jahed and Min Ke and Krzysztof Matyjaszewski},
title = {Preparation of Linear and Star-Shaped Block Copolymers by ATRP Using Simultaneous Reverse and Normal Initiation Process in Bulk and Miniemulsion},
journal = {Macromolecules},
year = {2004},
volume = {37},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/ma035712z},
number = {7},
pages = {2434--2441},
doi = {10.1021/ma035712z}
}
Cite this
MLA
Copy
Li, Mei, et al. “Preparation of Linear and Star-Shaped Block Copolymers by ATRP Using Simultaneous Reverse and Normal Initiation Process in Bulk and Miniemulsion.” Macromolecules, vol. 37, no. 7, Mar. 2004, pp. 2434-2441. https://doi.org/10.1021/ma035712z.