Macromolecules

, volume 39 , issue 11 , pages 3786-3793

New Organometallic Polymers by Polycondensation of Ferrocene and Siloxane Derivatives

Maria Cazacu ¹

Angelica Vlad ¹

MIHAI MARCU ¹

Carmen Racles ¹

Anton Airinei ¹

Grigore Munteanu ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

“Petru Poni” Institute of Macromolecular Chemistry, Aleea Gr. Ghica Voda 41A, 700487, Iasi, Romania, and Chemistry Institute, Academy Street nr. 3, Moldavian Academy, Chishinew, Moldova MD-2028 |

Publication type: Journal Article

Publication date: 2006-04-26

American Chemical Society (ACS)

Macromolecules

scimago Q1

wos Q1

SJR: 1.352

CiteScore: 9.0

Impact factor: 5.2

ISSN: 00249297, 15205835

DOI: 10.1021/ma052030y

Copy DOI

Materials Chemistry

Organic Chemistry

Inorganic Chemistry

Polymers and Plastics

Abstract

A series of condensation polymers (polyesters and polyamides) of ferrocene and siloxane derivatives have been synthesized and characterized. Thus, 1,1‘-di(chlorocarbonyl)ferrocene (CAFc) and four different siloxane derivatives1,3-bis(aminopropyl)tetramethyldisiloxane) (AP0), α,ω-bis(3-aminopropyl)oligodimethylsiloxane (AP), 1,3-bis(hydroxypropyl)tetramethyldisiloxane (HP0), and 1,3-bis(p-hydroxyphenyleneazomethine-3-propyl)tetramethyldisiloxane (HBS0)were used as monomers for this purpose. A model polyamide was prepared by polycondensation of oxalyl chloride with AP0. This was analyzed as such or doped with ferrocene in order to appreciate the influence of the ferrocene units by comparison with the corresponding copolymer containing chemically linked ferrocene in the main chain. Thermal, mesomorphic, viscometric, and solubility behaviors of the obtained compounds were studied. Molecular masses were estimated by GPC. The polymers were investigated by cyclic voltammetry and UV−vis absorption spectroscopy in...

Found

2 citations

Ol'shevskaya Valentina

36 publications, 353 citations

h-index: 12

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

2 citations

Anisimov Anton

🥼 🤝

PhD in Chemistry

69 publications, 1 039 citations, 5 reviews

h-index: 19

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Moscow Institute of Physics and Technology

Tula State Pedagogical University named after L.N. Tolstoy

Research interests

"Smart" materials

Green chemistry

High molecular weight compounds

Organosilicon Chemistry

2 citations

Minyaylo Ekaterina

14 publications, 69 citations

h-index: 4

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Research interests

Dendrimers

Organosilicon Compounds

Polyhedral carboranes

Polymer science

1 citation

Vatsadze Sergey

DSc in Chemistry, professor, professor of the Russian Academy of Sciences

170 publications, 2 118 citations, 9 reviews

h-index: 20

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Research interests

Supramolecular chemistry

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GOST |

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Cazacu M. et al. New Organometallic Polymers by Polycondensation of Ferrocene and Siloxane Derivatives // Macromolecules. 2006. Vol. 39. No. 11. pp. 3786-3793.

GOST all authors (up to 50) Copy

Cazacu M., Vlad A., MARCU M., Racles C., Airinei A., Munteanu G. New Organometallic Polymers by Polycondensation of Ferrocene and Siloxane Derivatives // Macromolecules. 2006. Vol. 39. No. 11. pp. 3786-3793.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/ma052030y

UR - https://doi.org/10.1021/ma052030y

TI - New Organometallic Polymers by Polycondensation of Ferrocene and Siloxane Derivatives

T2 - Macromolecules

AU - Cazacu, Maria

AU - Vlad, Angelica

AU - MARCU, MIHAI

AU - Racles, Carmen

AU - Airinei, Anton

AU - Munteanu, Grigore

PY - 2006

DA - 2006/04/26

PB - American Chemical Society (ACS)

SP - 3786-3793

IS - 11

VL - 39

SN - 0024-9297

SN - 1520-5835

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2006_Cazacu,

author = {Maria Cazacu and Angelica Vlad and MIHAI MARCU and Carmen Racles and Anton Airinei and Grigore Munteanu},

title = {New Organometallic Polymers by Polycondensation of Ferrocene and Siloxane Derivatives},

journal = {Macromolecules},

year = {2006},

volume = {39},

publisher = {American Chemical Society (ACS)},

month = {apr},

url = {https://doi.org/10.1021/ma052030y},

number = {11},

pages = {3786--3793},

doi = {10.1021/ma052030y}

}

MLA

Cite this

MLA Copy

Cazacu, Maria, et al. “New Organometallic Polymers by Polycondensation of Ferrocene and Siloxane Derivatives.” Macromolecules, vol. 39, no. 11, Apr. 2006, pp. 3786-3793. https://doi.org/10.1021/ma052030y.

Publisher

American Chemical Society (ACS)

Journal

Macromolecules

scimago Q1

wos Q1

SJR

1.352

CiteScore

9.0

Impact factor

5.2

ISSN

00249297 (Print)

15205835 (Electronic)