Glass Transition Behavior of Clay Aerogel/Poly(vinyl alcohol) Composites
Publication type: Journal Article
Publication date: 2006-08-22
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
In polymer/clay nanocomposites, the size and morphology of the dispersed clay are crucial in determining the macroscopic composite properties. Clay can be converted into an aerogel structure through a freeze-drying process which results in a reduction of its density from 2.35 to 0.05 g/cm3. The morphology of these clay aerogels resembles a house of cards structure. Low weight fraction (0.5−4 wt %) composites of clay and clay aerogel with a poly(vinyl alcohol) (PVOH) matrix polymer were prepared. Glass transition temperature (Tg) behaviors of clay/PVOH composites were investigated as a function of size, loading, and dispersion of clay and clay aerogel in the polymer matrix. The trends in Tg measured from both dynamic mechanical analysis and differential scanning calorimetry are similar, exhibiting a maximum value at 1 wt % loading for both clay and clay aerogel and then decreasing with additional filler content. Although the trends are similar, the drop in Tg at 4 wt % clay composite is considerably larger...
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118
Total citations:
118
Citations from 2024:
6
(5.08%)
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GOST
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Bandi S., Schiraldi D. A. Glass Transition Behavior of Clay Aerogel/Poly(vinyl alcohol) Composites // Macromolecules. 2006. Vol. 39. No. 19. pp. 6537-6545.
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Bandi S., Schiraldi D. A. Glass Transition Behavior of Clay Aerogel/Poly(vinyl alcohol) Composites // Macromolecules. 2006. Vol. 39. No. 19. pp. 6537-6545.
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RIS
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TY - JOUR
DO - 10.1021/ma0611826
UR - https://doi.org/10.1021/ma0611826
TI - Glass Transition Behavior of Clay Aerogel/Poly(vinyl alcohol) Composites
T2 - Macromolecules
AU - Bandi, Suneel
AU - Schiraldi, David A.
PY - 2006
DA - 2006/08/22
PB - American Chemical Society (ACS)
SP - 6537-6545
IS - 19
VL - 39
SN - 0024-9297
SN - 1520-5835
ER -
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BibTex (up to 50 authors)
Copy
@article{2006_Bandi,
author = {Suneel Bandi and David A. Schiraldi},
title = {Glass Transition Behavior of Clay Aerogel/Poly(vinyl alcohol) Composites},
journal = {Macromolecules},
year = {2006},
volume = {39},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/ma0611826},
number = {19},
pages = {6537--6545},
doi = {10.1021/ma0611826}
}
Cite this
MLA
Copy
Bandi, Suneel, and David A. Schiraldi. “Glass Transition Behavior of Clay Aerogel/Poly(vinyl alcohol) Composites.” Macromolecules, vol. 39, no. 19, Aug. 2006, pp. 6537-6545. https://doi.org/10.1021/ma0611826.