Synthesis and Characterization of Hydroxyl-Functionalized Poly(propylene carbonate)
Publication type: Journal Article
Publication date: 2014-01-06
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
Hydroxyl-functionalized poly(propylene carbonate) (PPC) was synthesized by a zinc glutarate catalyst mediated terpolymerization of carbon dioxide (CO2), propylene oxide (PO), and 2-[[(2-nitrophenyl)methoxy]methyl]oxirane (monomer A). PPC with varying monomer A contents (0–10.6 mol %) were obtained and could be transformed into hydroxyl-functionalized PPC by ultraviolet (UV) light irradiation without backbone degradation. The process of removing o-nitrobenzyl (ONB) protecting groups was monitored by UV–vis spectrometry to proceed within minutes. Thermal properties and contact angles of the functionalized PPCs were measured, showing the expected increase in hydrophilicity and glass transition temperature with increasing content of hydroxyl entities.
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48
Total citations:
48
Citations from 2025:
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(6.25%)
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GOST
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Wu X. et al. Synthesis and Characterization of Hydroxyl-Functionalized Poly(propylene carbonate) // Macromolecules. 2014. Vol. 47. No. 2. pp. 492-497.
GOST all authors (up to 50)
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Wu X., Zhao H., Nörnberg B., Théato P., Luinstra G. A. Synthesis and Characterization of Hydroxyl-Functionalized Poly(propylene carbonate) // Macromolecules. 2014. Vol. 47. No. 2. pp. 492-497.
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RIS
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TY - JOUR
DO - 10.1021/ma401899h
UR - https://doi.org/10.1021/ma401899h
TI - Synthesis and Characterization of Hydroxyl-Functionalized Poly(propylene carbonate)
T2 - Macromolecules
AU - Wu, Xiaojun
AU - Zhao, Hui
AU - Nörnberg, Benjamin
AU - Théato, Patrick
AU - Luinstra, Gerrit A.
PY - 2014
DA - 2014/01/06
PB - American Chemical Society (ACS)
SP - 492-497
IS - 2
VL - 47
SN - 0024-9297
SN - 1520-5835
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Wu,
author = {Xiaojun Wu and Hui Zhao and Benjamin Nörnberg and Patrick Théato and Gerrit A. Luinstra},
title = {Synthesis and Characterization of Hydroxyl-Functionalized Poly(propylene carbonate)},
journal = {Macromolecules},
year = {2014},
volume = {47},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/ma401899h},
number = {2},
pages = {492--497},
doi = {10.1021/ma401899h}
}
Cite this
MLA
Copy
Wu, Xiaojun, et al. “Synthesis and Characterization of Hydroxyl-Functionalized Poly(propylene carbonate).” Macromolecules, vol. 47, no. 2, Jan. 2014, pp. 492-497. https://doi.org/10.1021/ma401899h.