Effect of Reaction Parameters on the Molecular Weights of Polymers Formed in a Suzuki Polycondensation
Publication type: Journal Article
Publication date: 2008-10-04
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
A comprehensive investigation was undertaken in order to determine the effect of different reaction parameters on the molecular weights of polymers formed in a Suzuki polycondensation. In particular, we studied how the choice of solvent, base, ligand cocatalyst, palladium source, and monomers could affect the molecular weights. For these particular polymerizations, the best solvent and base were found to be CH2Cl2 and aqueous 3 M K3PO4, respectively. More interestingly, we determined that tri(o-tolyl)phosphine far surpassed not only the traditional triphenylphospine ligand cocatalyst, but also the more-recently developed hindered, electron-rich ligands that have yielded impressive results in small-molecule Suzuki coupling reactions. Molecular weights were also found to depend upon the source of palladium, with bis[tri(o-tolyl)phosphine]palladium(0) providing the best overall catalyst system. Finally, contrary to earlier reports, we found no advantage to replacing the more readily accessible bromide monome...
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68
Total citations:
68
Citations from 2024:
3
(4.41%)
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GOST
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Murage J. et al. Effect of Reaction Parameters on the Molecular Weights of Polymers Formed in a Suzuki Polycondensation // Macromolecules. 2008. Vol. 41. No. 20. pp. 7330-7338.
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Murage J., Eddy J. W., Zimbalist J. R., Mcintyre T. B., Wagner Z. R., Goodson F. Effect of Reaction Parameters on the Molecular Weights of Polymers Formed in a Suzuki Polycondensation // Macromolecules. 2008. Vol. 41. No. 20. pp. 7330-7338.
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RIS
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TY - JOUR
DO - 10.1021/ma801275y
UR - https://doi.org/10.1021/ma801275y
TI - Effect of Reaction Parameters on the Molecular Weights of Polymers Formed in a Suzuki Polycondensation
T2 - Macromolecules
AU - Murage, Joy
AU - Eddy, Jennifer W
AU - Zimbalist, Jennifer R
AU - Mcintyre, Tia B
AU - Wagner, Zachary R
AU - Goodson, Felix
PY - 2008
DA - 2008/10/04
PB - American Chemical Society (ACS)
SP - 7330-7338
IS - 20
VL - 41
SN - 0024-9297
SN - 1520-5835
ER -
Cite this
BibTex (up to 50 authors)
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@article{2008_Murage,
author = {Joy Murage and Jennifer W Eddy and Jennifer R Zimbalist and Tia B Mcintyre and Zachary R Wagner and Felix Goodson},
title = {Effect of Reaction Parameters on the Molecular Weights of Polymers Formed in a Suzuki Polycondensation},
journal = {Macromolecules},
year = {2008},
volume = {41},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/ma801275y},
number = {20},
pages = {7330--7338},
doi = {10.1021/ma801275y}
}
Cite this
MLA
Copy
Murage, Joy, et al. “Effect of Reaction Parameters on the Molecular Weights of Polymers Formed in a Suzuki Polycondensation.” Macromolecules, vol. 41, no. 20, Oct. 2008, pp. 7330-7338. https://doi.org/10.1021/ma801275y.