Reaction Kinetics and Simulations for Solid-State Polymerization of Poly(ethylene terephthalate)
1
Light Industry and Textile College, Sichuan Union University, Chengdu 610065, China
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2
Yizheng Chemical Fiber Limited Company, Jiangsu, Yizheng 211451, China
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Publication type: Journal Article
Publication date: 1997-11-01
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
A comprehensive model for solid-state polymerization of poly(ethylene terephthalate) was developed from analyzing the similarities and the differences between solid-state and melt polymerization. Considering the end groups diffusion limitation and the modification of concentrations of end groups and byproducts in the amorphous phase, a system of mass transfer and balance equations suitable for the solid-state polymerization of PET were obtained, based on simplifying the reaction kinetics of melt polymerization of PET. The degradation and other side reactions neglected in the earlier models for the solid-state polymerization of PET were included in the model. This simulation gave a quantitative prediction in the effect of temperature, particle size, starting molecular weight, and ratio of end groups on the degree of polymerization of products during the solid-state polymerization of poly(ethylene terephthalate). These simulation results were in agreement with experiments.
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69
Total citations:
69
Citations from 2024:
2
(2.9%)
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GOST
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Wu D. et al. Reaction Kinetics and Simulations for Solid-State Polymerization of Poly(ethylene terephthalate) // Macromolecules. 1997. Vol. 30. No. 22. pp. 6737-6742.
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Wu D., Chen F., Li R., Shi Y. Reaction Kinetics and Simulations for Solid-State Polymerization of Poly(ethylene terephthalate) // Macromolecules. 1997. Vol. 30. No. 22. pp. 6737-6742.
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RIS
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TY - JOUR
DO - 10.1021/ma9612541
UR - https://doi.org/10.1021/ma9612541
TI - Reaction Kinetics and Simulations for Solid-State Polymerization of Poly(ethylene terephthalate)
T2 - Macromolecules
AU - Wu, Dacheng
AU - Chen, Feng
AU - Li, Ruixia
AU - Shi, Youdong
PY - 1997
DA - 1997/11/01
PB - American Chemical Society (ACS)
SP - 6737-6742
IS - 22
VL - 30
SN - 0024-9297
SN - 1520-5835
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1997_Wu,
author = {Dacheng Wu and Feng Chen and Ruixia Li and Youdong Shi},
title = {Reaction Kinetics and Simulations for Solid-State Polymerization of Poly(ethylene terephthalate)},
journal = {Macromolecules},
year = {1997},
volume = {30},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/ma9612541},
number = {22},
pages = {6737--6742},
doi = {10.1021/ma9612541}
}
Cite this
MLA
Copy
Wu, Dacheng, et al. “Reaction Kinetics and Simulations for Solid-State Polymerization of Poly(ethylene terephthalate).” Macromolecules, vol. 30, no. 22, Nov. 1997, pp. 6737-6742. https://doi.org/10.1021/ma9612541.