From Heterogeneous to Homogeneous Nucleation of Isotactic Poly(propylene) Confined to Nanoporous Alumina
3
Institut fuer Chemie, Universitaet Osnabrueck, D-49069 Osnabrueck, Germany
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5
Foundation for Research and Technology (FORTH), Biomedical Research Institute, Ioannina, Greece
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Publication type: Journal Article
Publication date: 2011-02-28
scimago Q1
wos Q1
SJR: 2.967
CiteScore: 14.9
Impact factor: 9.1
ISSN: 15306984, 15306992
PubMed ID:
21355534
General Chemistry
Condensed Matter Physics
General Materials Science
Mechanical Engineering
Bioengineering
Abstract
The crystallization of highly isotactic polypropylene confined in self-ordered nanoporous alumina is studied by differential scanning calorimetry. A transformation from a predominantly heterogeneous to predominantly homogeneous nucleation takes place if the pore diameter is smaller than 65 nm. Crystallization is suppressed with decreasing pore size, and the absence of nucleation below 20 nm pores indicates the critical nucleus size. The results reported here might enhance the understanding of nanocomposites containing semicrystalline polymers and reveal design criteria for polymeric nanofibers with tailored mechanical and optical properties.
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Citations from 2025:
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Duran H. et al. From Heterogeneous to Homogeneous Nucleation of Isotactic Poly(propylene) Confined to Nanoporous Alumina // Nano Letters. 2011. Vol. 11. No. 4. pp. 1671-1675.
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Duran H., Steinhart M., Butt H. J., Floudas G. From Heterogeneous to Homogeneous Nucleation of Isotactic Poly(propylene) Confined to Nanoporous Alumina // Nano Letters. 2011. Vol. 11. No. 4. pp. 1671-1675.
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RIS
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TY - JOUR
DO - 10.1021/nl200153c
UR - https://doi.org/10.1021/nl200153c
TI - From Heterogeneous to Homogeneous Nucleation of Isotactic Poly(propylene) Confined to Nanoporous Alumina
T2 - Nano Letters
AU - Duran, Hatice
AU - Steinhart, Martin
AU - Butt, Hans Jürgen
AU - Floudas, George
PY - 2011
DA - 2011/02/28
PB - American Chemical Society (ACS)
SP - 1671-1675
IS - 4
VL - 11
PMID - 21355534
SN - 1530-6984
SN - 1530-6992
ER -
Cite this
BibTex (up to 50 authors)
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@article{2011_Duran,
author = {Hatice Duran and Martin Steinhart and Hans Jürgen Butt and George Floudas},
title = {From Heterogeneous to Homogeneous Nucleation of Isotactic Poly(propylene) Confined to Nanoporous Alumina},
journal = {Nano Letters},
year = {2011},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/nl200153c},
number = {4},
pages = {1671--1675},
doi = {10.1021/nl200153c}
}
Cite this
MLA
Copy
Duran, Hatice, et al. “From Heterogeneous to Homogeneous Nucleation of Isotactic Poly(propylene) Confined to Nanoporous Alumina.” Nano Letters, vol. 11, no. 4, Feb. 2011, pp. 1671-1675. https://doi.org/10.1021/nl200153c.