Organic Letters

, том 4 , издание 8 , страницы 1245-1247

Synthesis of Phosphole-2,5-dicarboxylic Acids via a [1,5]-Shift of Carbon Dioxide around the Phosphole Nucleus

Тип публикации: Journal Article

Дата публикации: 2002-03-15

American Chemical Society (ACS)

Organic Letters

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CiteScore: 7.7

Impact factor: 4.7

ISSN: 15237060, 15237052

DOI: 10.1021/ol0102895

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PubMed ID: 11950333

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

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A new methodology for the synthesis of 1-P-functionalized phosphole-2,5-dicarboxylic acids is described. The carboxylic group is introduced through a two-step sequence which involves a preliminary attack of the phospholide unit onto CO(2) followed by a [1,5]-shift reaction of the CO(2)Li group around the phosphole nucleus. This approach was extended to the preparation of a new type of bidentate ligands. [reaction: see text]

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Melaimi M. et al. Synthesis of Phosphole-2,5-dicarboxylic Acids via a [1,5]-Shift of Carbon Dioxide around the Phosphole Nucleus // Organic Letters. 2002. Vol. 4. No. 8. pp. 1245-1247.

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Melaimi M., Ricard L., Mathey F., Le Floch P. Synthesis of Phosphole-2,5-dicarboxylic Acids via a [1,5]-Shift of Carbon Dioxide around the Phosphole Nucleus // Organic Letters. 2002. Vol. 4. No. 8. pp. 1245-1247.

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TY - JOUR

DO - 10.1021/ol0102895

UR - https://doi.org/10.1021/ol0102895

TI - Synthesis of Phosphole-2,5-dicarboxylic Acids via a [1,5]-Shift of Carbon Dioxide around the Phosphole Nucleus

T2 - Organic Letters

AU - Melaimi, Mohand

AU - Ricard, Louis

AU - Mathey, François

AU - Le Floch, Pascal

PY - 2002

DA - 2002/03/15

PB - American Chemical Society (ACS)

SP - 1245-1247

IS - 8

VL - 4

PMID - 11950333

SN - 1523-7060

SN - 1523-7052

ER -

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@article{2002_Melaimi,

author = {Mohand Melaimi and Louis Ricard and François Mathey and Pascal Le Floch},

title = {Synthesis of Phosphole-2,5-dicarboxylic Acids via a [1,5]-Shift of Carbon Dioxide around the Phosphole Nucleus},

journal = {Organic Letters},

year = {2002},

volume = {4},

publisher = {American Chemical Society (ACS)},

month = {mar},

url = {https://doi.org/10.1021/ol0102895},

number = {8},

pages = {1245--1247},

doi = {10.1021/ol0102895}

}

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Melaimi, Mohand, et al. “Synthesis of Phosphole-2,5-dicarboxylic Acids via a [1,5]-Shift of Carbon Dioxide around the Phosphole Nucleus.” Organic Letters, vol. 4, no. 8, Mar. 2002, pp. 1245-1247. https://doi.org/10.1021/ol0102895.

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American Chemical Society (ACS)

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Organic Letters

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