A superior method for the reduction of secondary phosphine oxides.
Тип публикации: Journal Article
Дата публикации: 2005-08-24
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 1.007
CiteScore: 7.7
Impact factor: 4.7
ISSN: 15237060, 15237052
PubMed ID:
16146406
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
[reaction: see text] Diisobutylaluminum hydride (DIBAL-H) and triisobutylaluminum have been found to be outstanding reductants for secondary phosphine oxides (SPOs). All classes of SPOs can be readily reduced, including diaryl, arylalkyl, and dialkyl members. Many SPOs can now be reduced at cryogenic temperatures, and conditions for preservation of reducible functional groups have been found. Even the most electron-rich and sterically hindered phosphine oxides can be reduced in a few hours at 50-70 degrees C. This new reduction has distinct advantages over existing technologies.
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ГОСТ
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Busacca C. A. et al. A superior method for the reduction of secondary phosphine oxides. // Organic Letters. 2005. Vol. 7. No. 19. pp. 4277-4280.
ГОСТ со всеми авторами (до 50)
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Busacca C. A., Lorenz J. C., Grinberg N., Haddad N., Hrapchak M., Latli B., Lee H., Sabila P., Saha A., Sarvestani M., Shen S., Varsolona R., Wei X., Senanayake C. H. A superior method for the reduction of secondary phosphine oxides. // Organic Letters. 2005. Vol. 7. No. 19. pp. 4277-4280.
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TY - JOUR
DO - 10.1021/ol0517832
UR - https://doi.org/10.1021/ol0517832
TI - A superior method for the reduction of secondary phosphine oxides.
T2 - Organic Letters
AU - Busacca, Carl A
AU - Lorenz, Jon C.
AU - Grinberg, Nelu
AU - Haddad, Nizar
AU - Hrapchak, Matt
AU - Latli, Bachir
AU - Lee, HeeWon
AU - Sabila, Paul
AU - Saha, Anjan
AU - Sarvestani, Max
AU - Shen, Sherry
AU - Varsolona, Richard
AU - Wei, Xudong
AU - Senanayake, Chris H.
PY - 2005
DA - 2005/08/24
PB - American Chemical Society (ACS)
SP - 4277-4280
IS - 19
VL - 7
PMID - 16146406
SN - 1523-7060
SN - 1523-7052
ER -
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BibTex (до 50 авторов)
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@article{2005_Busacca,
author = {Carl A Busacca and Jon C. Lorenz and Nelu Grinberg and Nizar Haddad and Matt Hrapchak and Bachir Latli and HeeWon Lee and Paul Sabila and Anjan Saha and Max Sarvestani and Sherry Shen and Richard Varsolona and Xudong Wei and Chris H. Senanayake},
title = {A superior method for the reduction of secondary phosphine oxides.},
journal = {Organic Letters},
year = {2005},
volume = {7},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/ol0517832},
number = {19},
pages = {4277--4280},
doi = {10.1021/ol0517832}
}
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MLA
Скопировать
Busacca, Carl A., et al. “A superior method for the reduction of secondary phosphine oxides..” Organic Letters, vol. 7, no. 19, Aug. 2005, pp. 4277-4280. https://doi.org/10.1021/ol0517832.
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