American Chemical Society (ACS)
Organic Letters
,  том 14 ,  издание 23 ,  страницы 6040-6043

Facile and Exclusive Formation of Aziridinofullerenes by Acid-catalyzed Denitrogenation of Triazolinofullerenes

Тип публикации: Journal Article
Дата публикации: 2012-11-27
American Chemical Society (ACS)
scimago Q1
wos Q1
БС1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5
ISSN: 15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
Variously substituted [6,6]closed aziridinofullerenes were exclusively obtained from acid-catalyzed denitrogenation of triazolinofullerenes without formation of relevant [5,6]open azafulleroids, which are the major products on noncatalyzed denitrogenation. The mechanistic consideration by DFT calculations suggested a reaction sequence involving initial pre-equilibrium protonation of the triazoline N1 atom, generation of aminofullerenyl cation by nitrogen-extrusion, and final aziridination.
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Ikuma N. et al. Facile and Exclusive Formation of Aziridinofullerenes by Acid-catalyzed Denitrogenation of Triazolinofullerenes // Organic Letters. 2012. Vol. 14. No. 23. pp. 6040-6043.
ГОСТ со всеми авторами (до 50) Скопировать
Ikuma N., Mikie T., Doi Y., Nakagawa K., Kokubo K., Oshima T. Facile and Exclusive Formation of Aziridinofullerenes by Acid-catalyzed Denitrogenation of Triazolinofullerenes // Organic Letters. 2012. Vol. 14. No. 23. pp. 6040-6043.
RIS |
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TY - JOUR
DO - 10.1021/ol302928d
UR - https://doi.org/10.1021/ol302928d
TI - Facile and Exclusive Formation of Aziridinofullerenes by Acid-catalyzed Denitrogenation of Triazolinofullerenes
T2 - Organic Letters
AU - Ikuma, Naohiko
AU - Mikie, Tsubasa
AU - Doi, Yuta
AU - Nakagawa, Koji
AU - Kokubo, Ken
AU - Oshima, Takumi
PY - 2012
DA - 2012/11/27
PB - American Chemical Society (ACS)
SP - 6040-6043
IS - 23
VL - 14
PMID - 23185974
SN - 1523-7060
SN - 1523-7052
ER -
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@article{2012_Ikuma,
author = {Naohiko Ikuma and Tsubasa Mikie and Yuta Doi and Koji Nakagawa and Ken Kokubo and Takumi Oshima},
title = {Facile and Exclusive Formation of Aziridinofullerenes by Acid-catalyzed Denitrogenation of Triazolinofullerenes},
journal = {Organic Letters},
year = {2012},
volume = {14},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/ol302928d},
number = {23},
pages = {6040--6043},
doi = {10.1021/ol302928d}
}
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Ikuma, Naohiko, et al. “Facile and Exclusive Formation of Aziridinofullerenes by Acid-catalyzed Denitrogenation of Triazolinofullerenes.” Organic Letters, vol. 14, no. 23, Nov. 2012, pp. 6040-6043. https://doi.org/10.1021/ol302928d.