A Transition-Metal-Free Synthesis of Arylcarboxyamides from Aryl Diazonium Salts and Isocyanides
Publication type: Journal Article
Publication date: 2013-08-06
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
23919834
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A transition-metal-free carboxyamidation process, using aryl diazonium tetrafluoroborates and isocyanides under mild conditions, has been developed. This novel conversion was initiated by a base and solvent induced aryl radical, followed by radical addition to isocyanide and single electron transfer (SET) oxidation, affording the corresponding arylcarboxyamide upon hydration of the nitrilium intermediate.
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68
Total citations:
68
Citations from 2024:
9
(13.23%)
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GOST
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Xia Z., Zhu Q. A Transition-Metal-Free Synthesis of Arylcarboxyamides from Aryl Diazonium Salts and Isocyanides // Organic Letters. 2013. Vol. 15. No. 16. pp. 4110-4113.
GOST all authors (up to 50)
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Xia Z., Zhu Q. A Transition-Metal-Free Synthesis of Arylcarboxyamides from Aryl Diazonium Salts and Isocyanides // Organic Letters. 2013. Vol. 15. No. 16. pp. 4110-4113.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ol4017244
UR - https://doi.org/10.1021/ol4017244
TI - A Transition-Metal-Free Synthesis of Arylcarboxyamides from Aryl Diazonium Salts and Isocyanides
T2 - Organic Letters
AU - Xia, Zhonghua
AU - Zhu, Qiang
PY - 2013
DA - 2013/08/06
PB - American Chemical Society (ACS)
SP - 4110-4113
IS - 16
VL - 15
PMID - 23919834
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2013_Xia,
author = {Zhonghua Xia and Qiang Zhu},
title = {A Transition-Metal-Free Synthesis of Arylcarboxyamides from Aryl Diazonium Salts and Isocyanides},
journal = {Organic Letters},
year = {2013},
volume = {15},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/ol4017244},
number = {16},
pages = {4110--4113},
doi = {10.1021/ol4017244}
}
Cite this
MLA
Copy
Xia, Zhonghua, and Qiang Zhu. “A Transition-Metal-Free Synthesis of Arylcarboxyamides from Aryl Diazonium Salts and Isocyanides.” Organic Letters, vol. 15, no. 16, Aug. 2013, pp. 4110-4113. https://doi.org/10.1021/ol4017244.