Rh(II)-Catalyzed Reactions of Differentially Substituted Bis(diazo) Functionalities
Publication type: Journal Article
Publication date: 2013-07-26
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
23889290
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
The chemoselective reaction of donor/acceptor (D/A) and acceptor/acceptor (A/A) diazo moieties in the same molecule was examined using 3-diazo-1-(ethyl 2-diazomalonyl)indolin-2-one under rhodium(II) catalysis. The D/A diazo group undergoes selective cyclopropanation as well as XH-insertion, leaving behind the second diazo group for a further intramolecular dipolar cycloaddition reaction.
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Total citations:
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Citations from 2025:
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(10%)
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GOST
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Bonderoff S. A., Padwa A. Rh(II)-Catalyzed Reactions of Differentially Substituted Bis(diazo) Functionalities // Organic Letters. 2013. Vol. 15. No. 16. pp. 4114-4117.
GOST all authors (up to 50)
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Bonderoff S. A., Padwa A. Rh(II)-Catalyzed Reactions of Differentially Substituted Bis(diazo) Functionalities // Organic Letters. 2013. Vol. 15. No. 16. pp. 4114-4117.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ol4017468
UR - https://doi.org/10.1021/ol4017468
TI - Rh(II)-Catalyzed Reactions of Differentially Substituted Bis(diazo) Functionalities
T2 - Organic Letters
AU - Bonderoff, Sara A.
AU - Padwa, Albert
PY - 2013
DA - 2013/07/26
PB - American Chemical Society (ACS)
SP - 4114-4117
IS - 16
VL - 15
PMID - 23889290
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2013_Bonderoff,
author = {Sara A. Bonderoff and Albert Padwa},
title = {Rh(II)-Catalyzed Reactions of Differentially Substituted Bis(diazo) Functionalities},
journal = {Organic Letters},
year = {2013},
volume = {15},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/ol4017468},
number = {16},
pages = {4114--4117},
doi = {10.1021/ol4017468}
}
Cite this
MLA
Copy
Bonderoff, Sara A., and Albert Padwa. “Rh(II)-Catalyzed Reactions of Differentially Substituted Bis(diazo) Functionalities.” Organic Letters, vol. 15, no. 16, Jul. 2013, pp. 4114-4117. https://doi.org/10.1021/ol4017468.