Rh-catalyzed sequential oxidative C-H and N-N bond activation: conversion of azines into isoquinolines with air at room temperature.
Publication type: Journal Article
Publication date: 2014-06-16
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
24932667
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A rhodium-catalyzed sequential oxidative C-H annulation reaction between ketazines and internal alkynes has been developed via C-H and N-N bond activation with air as an external oxidant, which led to an efficient approach toward isoquinolines with high atom efficiency at rt. Utilizing the distinctive reactivity of this catalysis, both N-atoms of the azines could be efficiently incorporated to the desired isoquinolines under very robust and mild reaction conditions.
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137
Total citations:
137
Citations from 2025:
9
(6.57%)
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GOST
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Han W. et al. Rh-catalyzed sequential oxidative C-H and N-N bond activation: conversion of azines into isoquinolines with air at room temperature. // Organic Letters. 2014. Vol. 16. No. 13. pp. 3532-3535.
GOST all authors (up to 50)
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Han W., Zhang G., Li G., Huang H. Rh-catalyzed sequential oxidative C-H and N-N bond activation: conversion of azines into isoquinolines with air at room temperature. // Organic Letters. 2014. Vol. 16. No. 13. pp. 3532-3535.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ol501483k
UR - https://doi.org/10.1021/ol501483k
TI - Rh-catalyzed sequential oxidative C-H and N-N bond activation: conversion of azines into isoquinolines with air at room temperature.
T2 - Organic Letters
AU - Han, Wenjia
AU - Zhang, Guoying
AU - Li, Guangxing
AU - Huang, Hanmin
PY - 2014
DA - 2014/06/16
PB - American Chemical Society (ACS)
SP - 3532-3535
IS - 13
VL - 16
PMID - 24932667
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Han,
author = {Wenjia Han and Guoying Zhang and Guangxing Li and Hanmin Huang},
title = {Rh-catalyzed sequential oxidative C-H and N-N bond activation: conversion of azines into isoquinolines with air at room temperature.},
journal = {Organic Letters},
year = {2014},
volume = {16},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/ol501483k},
number = {13},
pages = {3532--3535},
doi = {10.1021/ol501483k}
}
Cite this
MLA
Copy
Han, Wenjia, et al. “Rh-catalyzed sequential oxidative C-H and N-N bond activation: conversion of azines into isoquinolines with air at room temperature..” Organic Letters, vol. 16, no. 13, Jun. 2014, pp. 3532-3535. https://doi.org/10.1021/ol501483k.