Organic Letters

, том 10 , издание 5 , страницы 933-935

Triflic Acid-Catalyzed Highly Stereoselective Friedel−Crafts Aminoalkylation of Indoles and Pyrroles

Тип публикации: Journal Article

Дата публикации: 2008-02-07

American Chemical Society (ACS)

Organic Letters

scimago Q1

wos Q1

БС1

SJR: 1.235

CiteScore: 8.7

Impact factor: 5

ISSN: 15237060, 15237052

DOI: 10.1021/ol703095d

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PubMed ID: 18254637

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

Краткое описание

A simple and efficient synthesis to both enantiomers of highly enantiomerically enriched alpha-trifluoromethyl-alpha-(heteroaryl)-glycine derivatives via highly stereoselective aminoalkylation of indoles and pyrroles is described. The triflic acid-catalyzed reaction of enantiomeric 3,3,3-trifluoro-pyruvate-alpha-methylbenzyl imines with indoles and pyrroles and the subsequent Pd-catalyzed hydrogenolysis of the methylbenzyl group provided the products in high yields and excellent enantioselectivities.

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ABID M., Teixeira L., Torok B. Triflic Acid-Catalyzed Highly Stereoselective Friedel−Crafts Aminoalkylation of Indoles and Pyrroles // Organic Letters. 2008. Vol. 10. No. 5. pp. 933-935.

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ABID M., Teixeira L., Torok B. Triflic Acid-Catalyzed Highly Stereoselective Friedel−Crafts Aminoalkylation of Indoles and Pyrroles // Organic Letters. 2008. Vol. 10. No. 5. pp. 933-935.

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TY - JOUR

DO - 10.1021/ol703095d

UR - https://doi.org/10.1021/ol703095d

TI - Triflic Acid-Catalyzed Highly Stereoselective Friedel−Crafts Aminoalkylation of Indoles and Pyrroles

T2 - Organic Letters

AU - ABID, MOHAMMED

AU - Teixeira, Liliana

AU - Torok, Bela

PY - 2008

DA - 2008/02/07

PB - American Chemical Society (ACS)

SP - 933-935

IS - 5

VL - 10

PMID - 18254637

SN - 1523-7060

SN - 1523-7052

ER -

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@article{2008_ABID,

author = {MOHAMMED ABID and Liliana Teixeira and Bela Torok},

title = {Triflic Acid-Catalyzed Highly Stereoselective Friedel−Crafts Aminoalkylation of Indoles and Pyrroles},

journal = {Organic Letters},

year = {2008},

volume = {10},

publisher = {American Chemical Society (ACS)},

month = {feb},

url = {https://doi.org/10.1021/ol703095d},

number = {5},

pages = {933--935},

doi = {10.1021/ol703095d}

}

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ABID, MOHAMMED, et al. “Triflic Acid-Catalyzed Highly Stereoselective Friedel−Crafts Aminoalkylation of Indoles and Pyrroles.” Organic Letters, vol. 10, no. 5, Feb. 2008, pp. 933-935. https://doi.org/10.1021/ol703095d.

Издатель

American Chemical Society (ACS)

Журнал

Organic Letters

scimago Q1

wos Q1

БС1

SJR

1.235

CiteScore

8.7

Impact factor

ISSN

15237060 (Print)

15237052 (Electronic)