Molybdenum and Tungsten Complexes That Contain the Diamidoamine Ligands [(C6F5NCH2CH2)2NMe]2-, [(3,4,5-C6H2F3NCH2CH2)2NMe]2-, and [(3-CF3C6H4NCH2CH2)2NMe]2-
Publication type: Journal Article
Publication date: 2004-01-20
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Molybdenum and tungsten complexes have been prepared that contain three different types of diamidoamine ligands of the type [(ArNCH2CH2)2NMe]2- ([ArNMe]2-, where Ar = C6F5, 3,4,5-F3C6H2, 3-CF3C6H4). The starting materials, which are of the type [Et3NH]{[ArNMe]MCl3}, are prepared from MCl4 reagents and the ligand upon addition of triethylamine. X-ray studies for [Et3NH]{[C6F5NMe]MoCl3}, [Et3NH]{[C6F5NMe]WCl3}, and [Bu4N]{[3-CF3C6H4NMe]MoCl3} reveal that the amido nitrogens are approximately cis to one another in a distorted-pseudooctahedral environment. Addition of various alkylating reagents to various [Et3NH]{[ArNMe]MCl3} species led to the formation of [C6F5NMe]MoMe2 (3), [C6F5NMe]Mo(CH2CMe3)Cl (4b), [C6F5NMe]W(CH2CMe3)Cl (5), [3,4,5-F3C6H2NMe]Mo(CH2CMe3)Cl (8), [3,4,5-F3C6H2NMe]Mo(CH2CMe3)(CCMe3) (9), [3,4,5-F3C6H2NMe]Mo(CH2SiMe3)2 (10), [3,4,5-F3C6H2NMe]W(CH2CMe3)(CCMe3) (11a), [3,4,5-F3C6H2NMe]W(CH2SiMe3)(CSiMe3) (11b), [3-CF3C6H4NMe]Mo(CH2SiMe3)2 (13), [3-CF3C6H4NMe]Mo(CH2CMe3)Cl (14), and [3-CF3C6H...
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Cochran F. V., Hock A. S., Schrock R. R. Molybdenum and Tungsten Complexes That Contain the Diamidoamine Ligands [(C6F5NCH2CH2)2NMe]2-, [(3,4,5-C6H2F3NCH2CH2)2NMe]2-, and [(3-CF3C6H4NCH2CH2)2NMe]2- // Organometallics. 2004. Vol. 23. No. 4. pp. 665-678.
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Cochran F. V., Hock A. S., Schrock R. R. Molybdenum and Tungsten Complexes That Contain the Diamidoamine Ligands [(C6F5NCH2CH2)2NMe]2-, [(3,4,5-C6H2F3NCH2CH2)2NMe]2-, and [(3-CF3C6H4NCH2CH2)2NMe]2- // Organometallics. 2004. Vol. 23. No. 4. pp. 665-678.
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TY - JOUR
DO - 10.1021/om030638u
UR - https://doi.org/10.1021/om030638u
TI - Molybdenum and Tungsten Complexes That Contain the Diamidoamine Ligands [(C6F5NCH2CH2)2NMe]2-, [(3,4,5-C6H2F3NCH2CH2)2NMe]2-, and [(3-CF3C6H4NCH2CH2)2NMe]2-
T2 - Organometallics
AU - Cochran, Frank V.
AU - Hock, Adam S.
AU - Schrock, R. R.
PY - 2004
DA - 2004/01/20
PB - American Chemical Society (ACS)
SP - 665-678
IS - 4
VL - 23
SN - 0276-7333
SN - 1520-6041
ER -
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@article{2004_Cochran,
author = {Frank V. Cochran and Adam S. Hock and R. R. Schrock},
title = {Molybdenum and Tungsten Complexes That Contain the Diamidoamine Ligands [(C6F5NCH2CH2)2NMe]2-, [(3,4,5-C6H2F3NCH2CH2)2NMe]2-, and [(3-CF3C6H4NCH2CH2)2NMe]2-},
journal = {Organometallics},
year = {2004},
volume = {23},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/om030638u},
number = {4},
pages = {665--678},
doi = {10.1021/om030638u}
}
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Cochran, Frank V., et al. “Molybdenum and Tungsten Complexes That Contain the Diamidoamine Ligands [(C6F5NCH2CH2)2NMe]2-, [(3,4,5-C6H2F3NCH2CH2)2NMe]2-, and [(3-CF3C6H4NCH2CH2)2NMe]2-.” Organometallics, vol. 23, no. 4, Jan. 2004, pp. 665-678. https://doi.org/10.1021/om030638u.