Neutron and X-ray diffraction studies and DFT calculations of asymmetric Bis(silyl) niobocene hydrides
Konstantin Yu Dorogov
1
,
Elise Dumont
1
,
Nam Nhat Ho
1
,
Nam-Nhat Ho
1
,
Josep Maria Poblet
1
,
Josep-Maria Poblet
1
,
Arthur J. Schultz
1
,
Judith A. K. Howard
1
,
Robert Bau
1
,
Agustí Lledós
1
,
Agusti Lledos
1
,
G. I. Nikonov
1
,
Georgii I. Nikonov
1
Publication type: Journal Article
Publication date: 2004-05-13
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The first asymmetric bis(silyl) niobocene hydrides Cp2Nb(SiHMe2)H(SiXMe2) (2: X = F (a), Cl (b), Br (c), I (d)), having interligand interactions Nb−H···Si−X, were prepared by selective halogenation of the Si−H bond in Cp2Nb(SiHMe2)2H. X-ray studies of 2b,c and a combined X-ray/neutron diffraction study of 2b establish a slightly stronger interaction of the niobium-bound hydride with the halosilyl ligand.
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25
Total citations:
25
Citations from 2024:
1
(4%)
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Dorogov K. Yu. et al. Neutron and X-ray diffraction studies and DFT calculations of asymmetric Bis(silyl) niobocene hydrides // Organometallics. 2004. Vol. 23. No. 12. pp. 2845-2847.
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Dorogov K. Yu., Dumont E., Ho N. N., Ho N., Churakov A. V., Kuz'mina L. G., Poblet J. M., Poblet J., Schultz A. J., Howard J. A. K., Bau R., Lledós A., Lledos A., Nikonov G. I., Nikonov G. I. Neutron and X-ray diffraction studies and DFT calculations of asymmetric Bis(silyl) niobocene hydrides // Organometallics. 2004. Vol. 23. No. 12. pp. 2845-2847.
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RIS
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TY - JOUR
DO - 10.1021/om034239a
UR - https://pubs.acs.org/doi/10.1021/om034239a
TI - Neutron and X-ray diffraction studies and DFT calculations of asymmetric Bis(silyl) niobocene hydrides
T2 - Organometallics
AU - Dorogov, Konstantin Yu
AU - Dumont, Elise
AU - Ho, Nam Nhat
AU - Ho, Nam-Nhat
AU - Churakov, Andrei V.
AU - Kuz'mina, Lyudmila G.
AU - Poblet, Josep Maria
AU - Poblet, Josep-Maria
AU - Schultz, Arthur J.
AU - Howard, Judith A. K.
AU - Bau, Robert
AU - Lledós, Agustí
AU - Lledos, Agusti
AU - Nikonov, G. I.
AU - Nikonov, Georgii I.
PY - 2004
DA - 2004/05/13
PB - American Chemical Society (ACS)
SP - 2845-2847
IS - 12
VL - 23
SN - 0276-7333
SN - 1520-6041
ER -
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BibTex (up to 50 authors)
Copy
@article{2004_Dorogov,
author = {Konstantin Yu Dorogov and Elise Dumont and Nam Nhat Ho and Nam-Nhat Ho and Andrei V. Churakov and Lyudmila G. Kuz'mina and Josep Maria Poblet and Josep-Maria Poblet and Arthur J. Schultz and Judith A. K. Howard and Robert Bau and Agustí Lledós and Agusti Lledos and G. I. Nikonov and Georgii I. Nikonov},
title = {Neutron and X-ray diffraction studies and DFT calculations of asymmetric Bis(silyl) niobocene hydrides},
journal = {Organometallics},
year = {2004},
volume = {23},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://pubs.acs.org/doi/10.1021/om034239a},
number = {12},
pages = {2845--2847},
doi = {10.1021/om034239a}
}
Cite this
MLA
Copy
Dorogov, Konstantin Yu., et al. “Neutron and X-ray diffraction studies and DFT calculations of asymmetric Bis(silyl) niobocene hydrides.” Organometallics, vol. 23, no. 12, May. 2004, pp. 2845-2847. https://pubs.acs.org/doi/10.1021/om034239a.
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