High-Resolution Mass-Analyzed Threshold Ionization Study of Deuterated Derivatives of Bis(η6-benzene)chromium
Publication type: Journal Article
Publication date: 2006-03-01
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Two-color multiphoton mass-analyzed threshold ionization (MATI) spectra of jet-cooled (η6-C6D6)2Cr and (η6-C6D5H)(η6-C6D6)Cr have been obtained for the first time with excitation of the sandwich molecules via vibronic components of the 3dz2 → R4px,y Rydberg transition. The ionization energies determined with extremely high accuracy (±0.0004 eV) on the basis of the MATI experiment are 5.4558 and 5.4562 eV, respectively. The simultaneous measurement of the two MATI spectra in one experiment reveals clearly the increase in the ionization energy caused by substitution of one deuterium atom in (η6-C6D6)2Cr with hydrogen. The MATI experiment demonstrates a nonlinear dependence of the ionization potential on the number of deuterium atoms in the bis(η6-benzene)chromium molecule. Deuteration appears to decrease both the ionization energy and the R4px,y Rydberg term value. The decrease in the term value is a result of the Jahn−Teller instability of the R4px,y Rydberg state. The ground-state cation vibrational frequ...
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Ketkov S. Y., Selzle H. L., Schlag E. W. High-Resolution Mass-Analyzed Threshold Ionization Study of Deuterated Derivatives of Bis(η6-benzene)chromium // Organometallics. 2006. Vol. 25. No. 7. pp. 1712-1716.
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Ketkov S. Y., Selzle H. L., Schlag E. W. High-Resolution Mass-Analyzed Threshold Ionization Study of Deuterated Derivatives of Bis(η6-benzene)chromium // Organometallics. 2006. Vol. 25. No. 7. pp. 1712-1716.
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RIS
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TY - JOUR
DO - 10.1021/om0509950
UR - https://doi.org/10.1021/om0509950
TI - High-Resolution Mass-Analyzed Threshold Ionization Study of Deuterated Derivatives of Bis(η6-benzene)chromium
T2 - Organometallics
AU - Ketkov, Sergey Yu.
AU - Selzle, Heinrich L.
AU - Schlag, Edward W.
PY - 2006
DA - 2006/03/01
PB - American Chemical Society (ACS)
SP - 1712-1716
IS - 7
VL - 25
SN - 0276-7333
SN - 1520-6041
ER -
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BibTex (up to 50 authors)
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@article{2006_Ketkov,
author = {Sergey Yu. Ketkov and Heinrich L. Selzle and Edward W. Schlag},
title = {High-Resolution Mass-Analyzed Threshold Ionization Study of Deuterated Derivatives of Bis(η6-benzene)chromium},
journal = {Organometallics},
year = {2006},
volume = {25},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/om0509950},
number = {7},
pages = {1712--1716},
doi = {10.1021/om0509950}
}
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Ketkov, Sergey Yu., et al. “High-Resolution Mass-Analyzed Threshold Ionization Study of Deuterated Derivatives of Bis(η6-benzene)chromium.” Organometallics, vol. 25, no. 7, Mar. 2006, pp. 1712-1716. https://doi.org/10.1021/om0509950.
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