Organometallics, volume 29, issue 10, pages 2199-2202

Formation of Methyl Acrylate from CO₂ and Ethylene via Methylation of Nickelalactones

Christian Bruckmeier ¹

Maximilian W Lehenmeier ¹

Robert Reichardt ¹

Sergei Vagin ¹

B. Rieger ¹

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Technische Universität München, WACKER-Lehrstuhl für Makromolekulare Chemie, Lichtenbergstrasse 4, 85748 Garching, Germany |

Publication type: Journal Article

Publication date: 2010-04-19

American Chemical Society (ACS)

Journal: Organometallics

scimago Q1

SJR: 0.654

CiteScore: 5.6

Impact factor: 2.5

ISSN: 02767333, 15206041

DOI: 10.1021/om100060y

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Organic Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Abstract

The nickel-induced coupling of ethylene and CO2 represents a promising pathway toward acrylates. To overcome the high bond dissociation energies of the M−O moieties, we worked out an in situ methylation of nickelalactones to realize the β-hydride elimination and the liberation of the acrylate species.

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Bruckmeier C. et al. Formation of Methyl Acrylate from CO2 and Ethylene via Methylation of Nickelalactones // Organometallics. 2010. Vol. 29. No. 10. pp. 2199-2202.

GOST all authors (up to 50) Copy

Bruckmeier C., Lehenmeier M. W., Reichardt R., Vagin S., Rieger B. Formation of Methyl Acrylate from CO2 and Ethylene via Methylation of Nickelalactones // Organometallics. 2010. Vol. 29. No. 10. pp. 2199-2202.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/om100060y

UR - https://doi.org/10.1021/om100060y

TI - Formation of Methyl Acrylate from CO2 and Ethylene via Methylation of Nickelalactones

T2 - Organometallics

AU - Bruckmeier, Christian

AU - Lehenmeier, Maximilian W

AU - Reichardt, Robert

AU - Vagin, Sergei

AU - Rieger, B.

PY - 2010

DA - 2010/04/19

PB - American Chemical Society (ACS)

SP - 2199-2202

IS - 10

VL - 29

SN - 0276-7333

SN - 1520-6041

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2010_Bruckmeier,

author = {Christian Bruckmeier and Maximilian W Lehenmeier and Robert Reichardt and Sergei Vagin and B. Rieger},

title = {Formation of Methyl Acrylate from CO2 and Ethylene via Methylation of Nickelalactones},

journal = {Organometallics},

year = {2010},

volume = {29},

publisher = {American Chemical Society (ACS)},

month = {apr},

url = {https://doi.org/10.1021/om100060y},

number = {10},

pages = {2199--2202},

doi = {10.1021/om100060y}

}

MLA

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MLA Copy

Bruckmeier, Christian, et al. “Formation of Methyl Acrylate from CO2 and Ethylene via Methylation of Nickelalactones.” Organometallics, vol. 29, no. 10, Apr. 2010, pp. 2199-2202. https://doi.org/10.1021/om100060y.

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Publisher

American Chemical Society (ACS)

Journal

Organometallics

scimago Q1

SJR

0.654

CiteScore

5.6

Impact factor

2.5

ISSN

02767333 (Print)

15206041 (Electronic)