Organometallics, volume 31, issue 1, pages 462-469

Thermal Switchability of N-Chelating Hoveyda-type Catalyst Containing a Secondary Amine Ligand

Karolina Żukowska 1, 2
Anna Szadkowska 1
Aleksandra E Pazio 2
Krzysztof Woźniak 2
1
 
Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland
Publication typeJournal Article
Publication date2011-12-13
Journal: Organometallics
scimago Q1
wos Q2
SJR0.654
CiteScore5.6
Impact factor2.5
ISSN02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
An investigation of aza analogues of the popular Hoveyda–Grubbs catalyst containing a secondary amine ligand is presented, proving the crucial impact of steric as well as electronic factors on the catalyst’s stability and performance. The issue of latency in the reactivity profile of studied catalysts is examined, followed by structural and application studies.
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