American Chemical Society (ACS)
Organometallics
,  том 31 ,  издание 12 ,  страницы 4429-4434

Enantiomerically Pure, Planar Chiral Cp*Ru Complexes: Synthesis, Molecular Structures, DFT and Coordination Properties

Тип публикации: Journal Article
Дата публикации: 2012-06-06
American Chemical Society (ACS)
scimago Q2
wos Q1
БС1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Reaction of (S)-1-(2-chlorophenyl)ethanol with [Cp*Ru(CH3CN)3][OTf] provides the single diastereomer (Sp)-[Cp*Ru(η6-(S)-1-(2-chlorophenyl)ethanol)][OTf] ((Sp,S)-1), in which the metal center is preferentially placed on one side of the arene ring. The other enantiomer (R)-1-(2-chlorophenyl)ethanol provides the planar chiral ruthenium compound (Rp,R)-1. The structures of both enantiomers were ascertained by single-crystal X-ray diffraction. These compounds can be used as precursors to prepare the enantiopure metalated phosphino ligands (Sp)-[Cp*Ru(η6-(S)-1-(2-diphenylphosphinophenyl)ethanol)][OTf] ((Sp,S)-2) and (Rp)-[Cp*Ru(η6-(R)-1-(2-diphenylphosphinophenyl)ethanol)][OTf] ((Rp,R)-2), in which the −PPh2 unit is attached to a chiral metalated π-arene platform. The chiral planar phosphine ligands react with [AuCl(tht)] to give heterobinuclear gold complexes with planar chirality, [AuCl((Sp,S)-2)] ((Sp,S)-3) and [AuCl((Rp,R)-2)] ((Rp,R)-3), as confirmed by their CD traces. Our method provides an entry to the ...
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Dubarle Offner J. et al. Enantiomerically Pure, Planar Chiral Cp*Ru Complexes: Synthesis, Molecular Structures, DFT and Coordination Properties // Organometallics. 2012. Vol. 31. No. 12. pp. 4429-4434.
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Dubarle Offner J., Axet M. R., Chamoreau L., Amouri H., Cooksy A. L. Enantiomerically Pure, Planar Chiral Cp*Ru Complexes: Synthesis, Molecular Structures, DFT and Coordination Properties // Organometallics. 2012. Vol. 31. No. 12. pp. 4429-4434.
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TY - JOUR
DO - 10.1021/om300210c
UR - https://doi.org/10.1021/om300210c
TI - Enantiomerically Pure, Planar Chiral Cp*Ru Complexes: Synthesis, Molecular Structures, DFT and Coordination Properties
T2 - Organometallics
AU - Dubarle Offner, Julien
AU - Axet, M Rosa
AU - Chamoreau, Lise-Marie
AU - Amouri, Hani
AU - Cooksy, Andrew L.
PY - 2012
DA - 2012/06/06
PB - American Chemical Society (ACS)
SP - 4429-4434
IS - 12
VL - 31
SN - 0276-7333
SN - 1520-6041
ER -
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@article{2012_Dubarle Offner,
author = {Julien Dubarle Offner and M Rosa Axet and Lise-Marie Chamoreau and Hani Amouri and Andrew L. Cooksy},
title = {Enantiomerically Pure, Planar Chiral Cp*Ru Complexes: Synthesis, Molecular Structures, DFT and Coordination Properties},
journal = {Organometallics},
year = {2012},
volume = {31},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/om300210c},
number = {12},
pages = {4429--4434},
doi = {10.1021/om300210c}
}
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Dubarle Offner, Julien, et al. “Enantiomerically Pure, Planar Chiral Cp*Ru Complexes: Synthesis, Molecular Structures, DFT and Coordination Properties.” Organometallics, vol. 31, no. 12, Jun. 2012, pp. 4429-4434. https://doi.org/10.1021/om300210c.