(η5-Cp*)Rh(III)/Ir(III) Complexes with Bis(chalcogenoethers) (E, E′ Ligands: E = S/Se; E′ = S/Se): Synthesis, Structure, and Applications in Catalytic Oppenauer-Type Oxidation and Transfer Hydrogenation
Publication type: Journal Article
Publication date: 2014-02-11
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The air- and moisture-insensitive half-sandwich complexes [(η5-Cp*)Rh(L)Cl][PF6] (1–3) and [(η5-Cp*)Ir(L)Cl][PF6] (4–6) have been prepared by reacting L = L1–L3 (1,2-bis(phenylthio)ethane (L1), 1-(phenylseleno)-2-(phenylthio)ethane (L2) and 1,2-bis(phenylseleno)ethane (L3)) with [(η5-Cp*)RhCl(μ-Cl)]2 and [(η5-Cp*)IrCl(μ-Cl)]2, respectively, at room temperature followed by treatment with NH4PF6. Their HR-MS and 1H, 13C{1H}, and 77Se{1H} NMR spectra have authenticated them. The single-crystal structures of 1–6 have been established by X-ray crystallography. Complexes 1–6 have been explored for catalytic Oppenauer-type oxidation of alcohols and transfer hydrogenation of ketones with 2-propanol. 3 and 6 were the most efficient in the two catalytic reactions (TON values up to 9.9 × 102 and 9.8 × 103, respectively) and were therefore investigated in detail. 3 is the first example of a Rh(III) species explored for Oppenauer-type oxidation. The catalysis appears to be homogeneous. In transfer hydrogenation it app...
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Prakash O. et al. (η5-Cp*)Rh(III)/Ir(III) Complexes with Bis(chalcogenoethers) (E, E′ Ligands: E = S/Se; E′ = S/Se): Synthesis, Structure, and Applications in Catalytic Oppenauer-Type Oxidation and Transfer Hydrogenation // Organometallics. 2014. Vol. 33. No. 4. pp. 983-993.
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Prakash O., Sharma K. N., Joshi H. N., Gupta P. L., Singh A. (η5-Cp*)Rh(III)/Ir(III) Complexes with Bis(chalcogenoethers) (E, E′ Ligands: E = S/Se; E′ = S/Se): Synthesis, Structure, and Applications in Catalytic Oppenauer-Type Oxidation and Transfer Hydrogenation // Organometallics. 2014. Vol. 33. No. 4. pp. 983-993.
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TY - JOUR
DO - 10.1021/om401150s
UR - https://doi.org/10.1021/om401150s
TI - (η5-Cp*)Rh(III)/Ir(III) Complexes with Bis(chalcogenoethers) (E, E′ Ligands: E = S/Se; E′ = S/Se): Synthesis, Structure, and Applications in Catalytic Oppenauer-Type Oxidation and Transfer Hydrogenation
T2 - Organometallics
AU - Prakash, Om
AU - Sharma, Kamal Nayan
AU - Joshi, Hemant N.
AU - Gupta, Pancham L
AU - Singh, Ajai
PY - 2014
DA - 2014/02/11
PB - American Chemical Society (ACS)
SP - 983-993
IS - 4
VL - 33
SN - 0276-7333
SN - 1520-6041
ER -
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@article{2014_Prakash,
author = {Om Prakash and Kamal Nayan Sharma and Hemant N. Joshi and Pancham L Gupta and Ajai Singh},
title = {(η5-Cp*)Rh(III)/Ir(III) Complexes with Bis(chalcogenoethers) (E, E′ Ligands: E = S/Se; E′ = S/Se): Synthesis, Structure, and Applications in Catalytic Oppenauer-Type Oxidation and Transfer Hydrogenation},
journal = {Organometallics},
year = {2014},
volume = {33},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/om401150s},
number = {4},
pages = {983--993},
doi = {10.1021/om401150s}
}
Cite this
MLA
Copy
Prakash, Om, et al. “(η5-Cp*)Rh(III)/Ir(III) Complexes with Bis(chalcogenoethers) (E, E′ Ligands: E = S/Se; E′ = S/Se): Synthesis, Structure, and Applications in Catalytic Oppenauer-Type Oxidation and Transfer Hydrogenation.” Organometallics, vol. 33, no. 4, Feb. 2014, pp. 983-993. https://doi.org/10.1021/om401150s.