Pd–PEPPSI-Type Expanded Ring N-Heterocyclic Carbene Complexes: Synthesis, Characterization, and Catalytic Activity in Suzuki–Miyaura Cross Coupling
Publication type: Journal Article
Publication date: 2014-05-22
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The synthesis and characterization of the new six- and seven-membered Pd–PEPPSI-type N-heterocyclic carbene (NHC) complexes 3 and 4 is described. Complexes of the general formula [Pd(NHC)(3ClPy)Cl2] (NHC = 6- or 7-Mes, 3ClPy = 3-chloropyridine) are accessed via the oxidation of the well-defined parent palladium(0) complexes 1 and 2. Complexes 3 and 4 have been employed in Suzuki–Miyaura cross-coupling and catalytic dehalogenation of a range of aryl halide substrates.
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Dunsford J. J., Cavell K. J. Pd–PEPPSI-Type Expanded Ring N-Heterocyclic Carbene Complexes: Synthesis, Characterization, and Catalytic Activity in Suzuki–Miyaura Cross Coupling // Organometallics. 2014. Vol. 33. No. 11. pp. 2902-2905.
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Dunsford J. J., Cavell K. J. Pd–PEPPSI-Type Expanded Ring N-Heterocyclic Carbene Complexes: Synthesis, Characterization, and Catalytic Activity in Suzuki–Miyaura Cross Coupling // Organometallics. 2014. Vol. 33. No. 11. pp. 2902-2905.
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TY - JOUR
DO - 10.1021/om5003107
UR - https://doi.org/10.1021/om5003107
TI - Pd–PEPPSI-Type Expanded Ring N-Heterocyclic Carbene Complexes: Synthesis, Characterization, and Catalytic Activity in Suzuki–Miyaura Cross Coupling
T2 - Organometallics
AU - Dunsford, Jay J
AU - Cavell, Kingsley J.
PY - 2014
DA - 2014/05/22
PB - American Chemical Society (ACS)
SP - 2902-2905
IS - 11
VL - 33
SN - 0276-7333
SN - 1520-6041
ER -
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BibTex (up to 50 authors)
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@article{2014_Dunsford,
author = {Jay J Dunsford and Kingsley J. Cavell},
title = {Pd–PEPPSI-Type Expanded Ring N-Heterocyclic Carbene Complexes: Synthesis, Characterization, and Catalytic Activity in Suzuki–Miyaura Cross Coupling},
journal = {Organometallics},
year = {2014},
volume = {33},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/om5003107},
number = {11},
pages = {2902--2905},
doi = {10.1021/om5003107}
}
Cite this
MLA
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Dunsford, Jay J., and Kingsley J. Cavell. “Pd–PEPPSI-Type Expanded Ring N-Heterocyclic Carbene Complexes: Synthesis, Characterization, and Catalytic Activity in Suzuki–Miyaura Cross Coupling.” Organometallics, vol. 33, no. 11, May. 2014, pp. 2902-2905. https://doi.org/10.1021/om5003107.