Solid-State Structure and Solution Reactivity of [(Ph3P)4Ru(H)2] and Related Ru(II) Complexes Used in Catalysis: A Reinvestigation
Publication type: Journal Article
Publication date: 2014-12-03
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
X-ray analysis of [(Ph3P)4Ru(H)2] (1) prepared by a literature procedure [Young, R.; Wilkinson, G. Inorg. Synth. 1990, 28, 337] shows that 1 is cocrystallized with PPh3, explaining the previously reported observations of free phosphine in solutions of 1. Lattice PPh3-free forms of 1 have also been obtained, structurally characterized, and found to generate small quantities of uncoordinated PPh3 and another species (A) in solution. Against previous beliefs, however, A is not [(Ph3P)3Ru(H)2] (2), but [(Ph3P)3Ru(H2)(H)2] (3) that forms in the reaction of 1 with adventitious water. This reaction apparently occurs via PPh3 loss from 1 to give 2, followed by H2O coordination, Ru(H)(OH2)/Ru(H2)(OH) rearrangement, H2 loss, and dimerization to give [(Ph3P)4Ru2(H)2(μ-OH)2] (4). The H2 thus produced is trapped with 2 to give 3. Complexes 3·0.5C6H6, 3·2THF, 4·2H2O, [(Ph3P)3Ru(N2)(H)2] (5), and [(Ph3P)2(H)Ru(μ-H)3Ru(PPh3)3]·0.5THF (6·0.5THF) have been structurally characterized for the first time. Also for the first t...
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Samouei H. et al. Solid-State Structure and Solution Reactivity of [(Ph3P)4Ru(H)2] and Related Ru(II) Complexes Used in Catalysis: A Reinvestigation // Organometallics. 2014. Vol. 33. No. 24. pp. 7279-7283.
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Samouei H., Miloserdov F. M., Escudero-Adán E. C., Grushin V. V. Solid-State Structure and Solution Reactivity of [(Ph3P)4Ru(H)2] and Related Ru(II) Complexes Used in Catalysis: A Reinvestigation // Organometallics. 2014. Vol. 33. No. 24. pp. 7279-7283.
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RIS
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TY - JOUR
DO - 10.1021/om5010572
UR - https://doi.org/10.1021/om5010572
TI - Solid-State Structure and Solution Reactivity of [(Ph3P)4Ru(H)2] and Related Ru(II) Complexes Used in Catalysis: A Reinvestigation
T2 - Organometallics
AU - Samouei, Hamidreza
AU - Miloserdov, Fedor M
AU - Escudero-Adán, Eduardo C.
AU - Grushin, Vladimir V.
PY - 2014
DA - 2014/12/03
PB - American Chemical Society (ACS)
SP - 7279-7283
IS - 24
VL - 33
SN - 0276-7333
SN - 1520-6041
ER -
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@article{2014_Samouei,
author = {Hamidreza Samouei and Fedor M Miloserdov and Eduardo C. Escudero-Adán and Vladimir V. Grushin},
title = {Solid-State Structure and Solution Reactivity of [(Ph3P)4Ru(H)2] and Related Ru(II) Complexes Used in Catalysis: A Reinvestigation},
journal = {Organometallics},
year = {2014},
volume = {33},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/om5010572},
number = {24},
pages = {7279--7283},
doi = {10.1021/om5010572}
}
Cite this
MLA
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Samouei, Hamidreza, et al. “Solid-State Structure and Solution Reactivity of [(Ph3P)4Ru(H)2] and Related Ru(II) Complexes Used in Catalysis: A Reinvestigation.” Organometallics, vol. 33, no. 24, Dec. 2014, pp. 7279-7283. https://doi.org/10.1021/om5010572.