Compounds of Group 14 Elements with an Element-Element (E = Si, Ge, Sn) Bond: Effect of the Nature of the Element Atom
K V Zaitsev
1
,
Kirill V. Zaitsev
2
,
Elmira Kh. Lermontova
3, 4
,
В. А. Тафеенко
1
,
Viktor A. Tafeenko
2
,
B.N. Tarasevich
1
,
Boris N Tarasevich
2
,
Oleg Kh Poleshchuk
5, 6
,
Anastasia V Kharcheva
1, 2
,
Oleg M. Nikitin
1, 7
,
Galina S. Zaitseva
1, 2
,
Sergey S. Karlov
1, 2
Publication type: Journal Article
Publication date: 2015-05-29
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Two series of germanium compounds, (p-Tol)3Ge-MMe3 (M = Si (1), Ge (2), Sn (3)) and (Me3Si)3Ge-MPh3 (M = Ge (4), Sn (5)), were prepared using lithium or potassium intermediates. The changing of the reaction conditions results in trigermane Ph3Ge-Ge(SiMe3)2-GePh3 (6). The molecular structures of 1, 2, and 6 were investigated by X-ray analysis. By UV/visible spectroscopy it is established that introduction of a tin atom results in a significant bathochromic absorption shift. Furthermore, according to cyclic voltammetry, oxidation potentials decrease in the order 1 > 2 > 3. The electronic structures of 1–4 and related (Me3Si)3Ge-SiPh3 were investigated by DFT calculations. Fluorescence properties of 1–3 were studied in the solid state and in solution; for compound 3 phosphorescence (lifetime is 4.58 ms) is observed in the solid state.
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Citations from 2024:
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Zaitsev K. V. et al. Compounds of Group 14 Elements with an Element-Element (E = Si, Ge, Sn) Bond: Effect of the Nature of the Element Atom // Organometallics. 2015. Vol. 34. No. 12. pp. 2765-2774.
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Zaitsev K. V., Zaitsev K. V., Lermontova E. K., Churakov A. V., Тафеенко В. А., Tafeenko V. A., Tarasevich B., Tarasevich B. N., Poleshchuk O. Kh., Kharcheva A. V., Magdesieva T. V., Nikitin O. M., Zaitseva G. S., Karlov S. S. Compounds of Group 14 Elements with an Element-Element (E = Si, Ge, Sn) Bond: Effect of the Nature of the Element Atom // Organometallics. 2015. Vol. 34. No. 12. pp. 2765-2774.
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RIS
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TY - JOUR
DO - 10.1021/om501293t
UR - https://pubs.acs.org/doi/10.1021/om501293t
TI - Compounds of Group 14 Elements with an Element-Element (E = Si, Ge, Sn) Bond: Effect of the Nature of the Element Atom
T2 - Organometallics
AU - Zaitsev, K V
AU - Zaitsev, Kirill V.
AU - Lermontova, Elmira Kh.
AU - Churakov, Andrei V.
AU - Тафеенко, В. А.
AU - Tafeenko, Viktor A.
AU - Tarasevich, B.N.
AU - Tarasevich, Boris N
AU - Poleshchuk, Oleg Kh
AU - Kharcheva, Anastasia V
AU - Magdesieva, Tatiana V.
AU - Nikitin, Oleg M.
AU - Zaitseva, Galina S.
AU - Karlov, Sergey S.
PY - 2015
DA - 2015/05/29
PB - American Chemical Society (ACS)
SP - 2765-2774
IS - 12
VL - 34
SN - 0276-7333
SN - 1520-6041
ER -
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BibTex (up to 50 authors)
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@article{2015_Zaitsev,
author = {K V Zaitsev and Kirill V. Zaitsev and Elmira Kh. Lermontova and Andrei V. Churakov and В. А. Тафеенко and Viktor A. Tafeenko and B.N. Tarasevich and Boris N Tarasevich and Oleg Kh Poleshchuk and Anastasia V Kharcheva and Tatiana V. Magdesieva and Oleg M. Nikitin and Galina S. Zaitseva and Sergey S. Karlov},
title = {Compounds of Group 14 Elements with an Element-Element (E = Si, Ge, Sn) Bond: Effect of the Nature of the Element Atom},
journal = {Organometallics},
year = {2015},
volume = {34},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://pubs.acs.org/doi/10.1021/om501293t},
number = {12},
pages = {2765--2774},
doi = {10.1021/om501293t}
}
Cite this
MLA
Copy
Zaitsev, K. V., et al. “Compounds of Group 14 Elements with an Element-Element (E = Si, Ge, Sn) Bond: Effect of the Nature of the Element Atom.” Organometallics, vol. 34, no. 12, May. 2015, pp. 2765-2774. https://pubs.acs.org/doi/10.1021/om501293t.