volume 29 issue 6 pages 1339-1342

Binuclear 1,2-Diphosphacyclopentadienyl Manganese(I) Complexes: Synthesis, Structure and Magnetic Properties

Publication typeJournal Article
Publication date2010-02-19
scimago Q2
wos Q1
SJR0.676
CiteScore5.1
Impact factor2.9
ISSN02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The reaction of Mn(CO)5Br with 1-trimethyltin-3,4,5-triphenyl-1,2-diphosphacyclopenta-2,4-diene leads to formation of binuclear manganese(I) complexes with bridging 1,2-diphosphacyclopentadienyl ligands exhibiting magnetic properties apparently similar to Mn(II) compounds due to intramolecular redistribution of the electron density. Variation of peripheral ligands of binuclear complexes provides control over the magnitude of the magnetic moment, the contribution of the orbital magnetism, and the strength of the magnetic exchange.
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GOST Copy
Miluykov V. et al. Binuclear 1,2-Diphosphacyclopentadienyl Manganese(I) Complexes: Synthesis, Structure and Magnetic Properties // Organometallics. 2010. Vol. 29. No. 6. pp. 1339-1342.
GOST all authors (up to 50) Copy
Miluykov V., Bezkishko I., Krivolapov D., Kataeva O., Sinyashin O. G., Hey-Hawkins E., Parameswaran A., Krupskaya Y., Kataev V. E., Клингелер Р., Büchner B. Binuclear 1,2-Diphosphacyclopentadienyl Manganese(I) Complexes: Synthesis, Structure and Magnetic Properties // Organometallics. 2010. Vol. 29. No. 6. pp. 1339-1342.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/om900764q
UR - https://doi.org/10.1021/om900764q
TI - Binuclear 1,2-Diphosphacyclopentadienyl Manganese(I) Complexes: Synthesis, Structure and Magnetic Properties
T2 - Organometallics
AU - Miluykov, Vasili
AU - Bezkishko, Ilya
AU - Krivolapov, Dmitry
AU - Kataeva, O.N.
AU - Sinyashin, Oleg G.
AU - Hey-Hawkins, Evamarie
AU - Parameswaran, Anupama
AU - Krupskaya, Y.
AU - Kataev, V. E.
AU - Клингелер, Р.
AU - Büchner, B.
PY - 2010
DA - 2010/02/19
PB - American Chemical Society (ACS)
SP - 1339-1342
IS - 6
VL - 29
SN - 0276-7333
SN - 1520-6041
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2010_Miluykov,
author = {Vasili Miluykov and Ilya Bezkishko and Dmitry Krivolapov and O.N. Kataeva and Oleg G. Sinyashin and Evamarie Hey-Hawkins and Anupama Parameswaran and Y. Krupskaya and V. E. Kataev and Р. Клингелер and B. Büchner},
title = {Binuclear 1,2-Diphosphacyclopentadienyl Manganese(I) Complexes: Synthesis, Structure and Magnetic Properties},
journal = {Organometallics},
year = {2010},
volume = {29},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/om900764q},
number = {6},
pages = {1339--1342},
doi = {10.1021/om900764q}
}
MLA
Cite this
MLA Copy
Miluykov, Vasili, et al. “Binuclear 1,2-Diphosphacyclopentadienyl Manganese(I) Complexes: Synthesis, Structure and Magnetic Properties.” Organometallics, vol. 29, no. 6, Feb. 2010, pp. 1339-1342. https://doi.org/10.1021/om900764q.
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